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3.4 Reduced Manganese Oxides  117





                                   References  [98]  [99]  [100]  [101]  [102]  [103]  [104]




                                       γ ( ◦ )  90  120  90  90  90  90  120

                                       β( ◦ )  90  90  90  90  90  90  90

                                       α( ◦ )  90  90  90  90  90  90  90


                              oxide–hydroxides.  Lattice constants  c (pm)  b (pin)  458.0  289.0  471  332  571.0  525.0  942.0  814.0  943.0  943.0  944  815  473.4  332.2






                              manganese  (pm)  a  1076.0  332  880.0  814.0  943.0  815  332.2



                              oxides and  Space  group  Pnma  P3ml  B2 1 /d a  I4 1 /amd  Ia3  I4 1 /amd P  P3ml


                              manganese



                              for reduced  Symmetry  Orthorhombic  Trigonal  Orthorhombic  Tetragonal  Cubic  Tetragonal  Trigonal



                              Crystallographic data  Approximate  formula  α-MnOOH  β-MnOOH  γ -MnOOH  Mn 3 O 4  α-Mn 2 O 3  γ -Mn 2 O 3  Mn(OH) 2 a Nonstandard setting of this space group.








                              Table 3.4  Compound  or mineral  Groutite  Feitknechtite  Manganite  Hausmannite  Pyrochroite
   144   145   146   147   148   149   150   151   152   153   154