Page 252 - Handbook of Plastics Technologies
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ELASTOMERS


                             4.44                        CHAPTER 4


























                             SCHEME 14

                                TABLE 4.7  Recipes for Vulcanization by Phenolic Curatives, Quinone Derivatives, or
                                Maleimides *
                                                                IIR          SBR

                                                             1      2       1    2   NBR
                                 Zinc oxide                  5.00  5.00     –    –     –
                                 Lead peroxide (Pb O )       –    10.00     –    –     –
                                             3 4
                                 Stearic acid                1.00   –       –    –     –
                                 Phenolic curative          12.00   –       –    –     –
                                          †
                                   (SP-1056)
                                 Benzoquinonedioxime (GMF)   –     2.00     –    –     –
                                 m-Phenylenebismaleamide (HVA-2) ‡  –  –   0.85  0.85  3.00
                                 2-Benzothiazyl disulfide (MBTS)  –  –      2.00  –     –
                                 Dicumyl peroxide            –     –        –   0.30  0.30
                                                 **
                                 Vulcanization condition
                                 Temperature, °C             180   153     153  153   153
                                 Time, min                   30    20      25    25   30
                                *.Concentrations in phr.
                                †.Schenectady Chemicals.
                                ‡.Du Pont.
                                **.Conditions change depending on other aspects of the compositions.





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