Page 232 - Introduction to Colloid and Surface Chemistry

Colloid stability 221

distances. If this minimum is moderately deep compared with kT, it
should give rise to a loose, easily reversible flocculation. For small
particles (a < c. 10~ 8 m) the secondary minimum is never deep
enough for this to happen in those cases where the potential energy
maximum is high enough to prevent coagulation into the primary
minimum. If the particles are larger, flocculation in the secondary
minimum may cause observable effects.
Several colloidal systems containing anisodimensional particles,
such as iron oxide and tobacco mosaic virus sols, show reversible

-50 kT

Figure 8.3 The influence of electrolyte concentration, K, on the total potential energy
7
19
of interaction of two spherical particles: a = 10 ~ m; T = 298 K; z = 1; A,, = 2 x 10~ J;
19
^3 3 = 0.4 x JO" J; €/e 0 = 78.5; ifi d = 50 mV = 2kT/e. V R and V A calculated using
equations (8.7), (8.9) and (8.13)