Page 234 - Introduction to Colloid and Surface Chemistry

Colloid stability 223

Measurement of particle interactions

Owing to their fundamental interest and their practical importance in
issues such as colloid stability, much experimental effort has been
devoted to the measurement of electric double layer and van der
Waals interactions between macroscopic objects at close separations.
Such measurements involve balancing the force(s) to be measured
with an externally applied force.

Electric double layer interactions

106<2(x)
Ottewill and co-workers have used a compression method to
measure the double-layer repulsion between the plate-like particles
of sodium montmorillonite. This is a particularly suitable system for
such studies, since the particles are sufficiently thin (c. 1 nm) for van
der Waals forces to be unimportant and surface roughness is not a
problem. The dispersion was confined between a semipermeable filter
and an impermeable elastic membrane and an external pressure was
applied via a hydraulic fluid so that the volume concentration of
particles and, hence, the distance of separation between the particles
could be measured as a function of applied pressure.
In another method, Roberts and Tabor 201 measured the electric
double layer repulsion between a transparent rubber sphere and a
plane glass surface separated by surfactant solution. As the surfaces
were brought together, the double-layer interaction caused a distor-
tion of the rubber surface which was monitored interferometrically.
The results of these measurements are in reasonable agreement
with predictions based on electric double layer theory, especially at
separations greater than UK.

van der Waals interactions

Attractive forces between macroscopic objects have been measured
directly by a number of investigators. In the first experiment of this
kind, Deryagin and Abricossova 107 202 203 used a sensitive electronic
'
'
feed-back balance to measure the attraction for a planoconvex
polished quartz system from which all residual electric charge had
been removed. Relatively large separations were involved and the