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                                                  APPENDIX A. DERIVATION OF TRANSPORT EQUATIONS
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                            a pipe) of the flow. When Kn is very small (<10 ), the continuum approach is
                            considered valid. In engineering and environmental flows, therefore, the continuum
                            approach is adopted.
                            Control Volume
                            The notion of a controlvolume (CV) is very important in the continuum approach.
                            The CV may be defined as a region in space across the boundaries of which matter,
                            energy, and momentum may flow; it is a region within which source or sink of the
                            same quantities may prevail. Further, it is a region on which external forces may
                            act.
                               In general, a CV may be large or infinitesimally small. However, consistent with
                            the idea of a differential in a continuum, an infinitesimally small CV is considered.
                            Thus, when the laws are to be expressed through differential equations, the CV is
                            located within a moving fluid. Again, two approaches are possible:

                            1. a Lagrangian approach or
                            2. a Eulerian approach.
                               In the Lagrangian approach, the CV is considered to be moving with the fluid
                            as a whole. In the Eulerian approach, in contrast, the CV is assumed fixed in space
                            and the fluid is assumed to flow through and past the CV. Except when dealing
                            with certain types of unsteady flows (waves, for example), the Eulerian approach is
                            generallyusedforitsnotionalsimplicity.Also,measurementsmadeusingstationary
                            instruments can be directly compared with the solutions of differential equations
                            obtained using the Eulerian approach.
                               Finally, it is important to note that the fundamental laws define total flows of
                            mass, momentum, and energy not only in terms of magnitude but also in terms of
                            direction. In a general problem of convection, neither magnitude nor direction is
                            known a priori at different positions in the flowing fluid. The problem of ignorance
                            of direction is circumvented by resolving velocity, force, and scalar fluxes in three
                            directions that define the space.
                               In the derivations to follow, the three chosen directions will be along Cartesian
                            coordinates. The derivations are carried out using the continuum approach within a
                            Eulerian specification of the CV. Figure A.1 shows the considered CV of dimensions
                             x 1 ,  x 2 , and  x 3 located at (x 1 , x 2 , x 3 ) from a fixed origin.


                            A.2 Mass Conservation – Fluid Mixture

                            The law of conservation of mass states that
                                                               ˙
                                                                                      ˙
                                  Rate of accumulation of mass (M ac ) = Rate of mass in (M in )
                                                                                         ˙
                                                                      − Rate of mass out (M out ).
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