Page 166 - Lignocellulosic Biomass to Liquid Biofuels
P. 166

[45,46]        [47,48]     [36,49 56]                    [36,49,50,57,58]  (Continued)



                    can                    pH                        salts  of
          volatile  char  reduction  more  toxic  corrosion  steps  time  into

          of  and  temperature  requirement  production  size  requires  of  recovery  neutralization  residence  Presence  incorporated
          Production  products  High  Ash  Particle  costly  be  Process  research  Generation  inhibitors  Equipment  Request  Long  request  biomass







          liquid         energy  requirement  conditions  equipment  thermal  energyPractical  simple  lower  cost  to compared  hydrolysis  inhibitor  and  removal
          and  production  low  Ambient  and  technique            Reactor  if  acid  formation  Hemicellulose  lignin
          Gas            Very  Simple  Low                               Low


                main  from           of  with
            of  the  and                   not  is                   hydrolysis
            decomposition  of  of  hemicellulose  lignin  content  hydrolyze  hemicelluloses  sugar  yieldLignin  solubilized  hemicellulose  cellulose  conversion  removal

          Thermal  cellulose  Separation  portions  residual  cellulose  Lignin  decrease  Effective  high  High  fraction  High  Lignin




          cooling        kV/  duration  milliseconds)  H 2 SO 4 ,HCl,  for  (5%   high  ratio  60°C,  4 h  35°  v/v),

          then  condensing  (5 20  short  to   process  loads  solids  substrate/  for  (10% 40%  substrate/mixture)  H 2 SO 4  Solid/Liquid  NaOH,  120°C,  H 2 O 2
          T . 300°C,  and  voltage  High  for  cm)  (nano  (Dilute)  0.75% 5%  HNO 3 T 5 160°C 200°C  P 5 1 MPa  Continuous  low  10%  mixture)  process  Batch  loads  (Concentrated)  10% 30%  T 5 170°C 190°C  1:2  Dilute  h  24  Ca(OH) 2 ,  of  Adding  (0.5 2.15%  C






          waste  corn  switchgrass  chip,  switchgrass  wood  corn  bagasse,  wheat  rye  rice  switchgrass  corn  bagasse,  cane
          Wood,  cotton,  stover,  Wood  Poplar  stover,  straw,  straw,  hulls,  Hardwood,  stover,  leaves




                         electric    hydrolysis                      hydrolysis

          Pyrolysis      Pulsed  field  Chemical  Acid             Alkaline
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