Page 168 - Lignocellulosic Biomass to Liquid Biofuels
P. 168

References  [36]  [59 61]          [62,63]  [64,65]





                 of  ozone                       to
                 Request  of  toxic  investment  require  processSolutions  difficult  water  with  the


            Disadvantages  process  Costly  amount  large  of Formation  inhibitors  capital  High  solvents Organic  recycling  Costly  and  viscous  handle  viscosity  High  dilution  The  decreases  interactions





                 compound     removal  by-product  of   at  solvent  of


            Advantages  toxic  No  generation  lignin  Pure  as  Efficiently  dissolution  cellulose  Green  room  temperature  effective  Cost  Synthesis  nontoxic  compounds  Biocompatible  Highly  biodegradable





            changed  remove   of  solubilization  conversion  solubilization


            Composition  Effectively  lignin  hydrolysis  Total  hemicellulose  Lignin  Cellulose  Lignin





                                       or  min,
                  and           ethanol,  ethylene  triethylene  mixture  H 2 SO 4  30 60  20:1  to  30 min  sugars,  and  organic
                 room  temperature,  solvents  (methanol,  or  of  1%  pH 5 2.0 3.4  liquid/biomass  equal  urea,  acids,  other
            Procedure  Ozone,  pressure  Organic  acetone,  glycol,  glycol)  with  HCl  T 5 185°C,  Ionic  ratio  T 5 120°C,  Choline,  amino  several  acids





                 straw,   hay,  straw,  sugarcane  pine  straw,  and  stover  straw
            Feedstock  Wheat  bagasse,  peanut,  poplar,  sawdust,  green  pine  Wheat  bagasse,  poplar,  spruce,  Wheat  bagasse,  peanut,  poplar  corn  Rice
        (Continued)




        4.2                                    liquids  deep  eutectic  solvents
        Table  Pretreatment  process  Ozonolysis  Organosolv  Ionic  Natural
   163   164   165   166   167   168   169   170   171   172   173