Page 404 - Lindens Handbook of Batteries
P. 404

LiTHiUM PriMAry BATTerieS        14.69

                                      3.2
                                      3.0
                                      2.8
                                      2.6                                            85°C
                                                                                     60°C
                                     Voltage, V  2.4                                 45°C
                                                                                     20°C
                                      2.2
                                      2.0                                            0°C
                                      1.8
                                                                                     –20°C
                                      1.6
                                                                                     –40°C
                                      1.4
                                        0.001   0.01     0.1      1      10      100     1000   10000
                                                              Discharge current, mA
                                    FIGURE 14.67  Mid-point voltage for Li/CFx 2/3 A-size cylindrical battery as a function of temperature
                                    and discharge current.





                                                                                     8
                                                                 20°C                6 5
                                                           0°C
                                                  10
                                                Discharge current, mA/cm 3  6  –20°C  50°C  4 3 2 1.5 Discharge current, mA/g
                                                  8
                                                  5
                                                  4
                                                  3
                                                  2



                                                    6  8 10    20      40  60 80 100 150 1
                                                               Hours of service
                                              FIGURE  14.68  Service  life  of  Li/(CF)   cylindrical  battery  at  vari-
                                                                        n
                                              ous discharge rates and temperatures; 1.8 V end voltage. (Courtesy of
                                              Panasonic Corp. of North America.)

                                                                            2
                                Fig. 14.69, which shows the discharge characteristics of the   A-size cell at a 20-μA discharge rate
                                                                            3
                                over a period of 7 years. Voltage delay after storage is not apparent with these cells, except under
                                severe discharge conditions.

                    14.9.4  Cell and Battery Types
                                The Li/(CF)  batteries are manufactured in a number of coin, cylindrical, and pin configurations. The
                                         n
                                major electrical and physical characteristics of some of these batteries are listed in Table 14.21a and b.
   399   400   401   402   403   404   405   406   407   408   409