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2.2 Materials                                                                   9

                                 Table 2.1  Selected Properties of Crystalline Silicon
                                              9
                                                  –2
                                 Yield strength (10 Nm )               7
                                                  –2
                                 Knoop hardness (kgmm )                850
                                 Young’s modulus (GPa), (100) orientation  160
                                 Poisson’s ratio, (100) orientation    0.28
                                          –3
                                 Density (gcm )                        2.33
                                 Lattice constant (Å)                  5.435
                                                          –6
                                                            –1
                                 Thermal expansion coefficient (10 K )  2.6
                                                     –1
                                                       –1
                                 Thermal conductivity (Wm K )          157
                                            –1
                                              –1
                                 Specific heat (Jg K )                 0.7
                                 Melting point (°C)                    1,410
                                 Energy gap (eV)                       1.12
                                 Dielectric constant                   11.9
                                                     –1
                                                 7
                                 Dielectric strength (10 Vm )          3
                                                  –1 –1
                                                 2
                                 Electron mobility (cm V s )           1,450
                                              2
                                                –1 –1
                                 Hole mobility (cm V s )               505
                  can be thickened by epitaxy, the thicknesses of the SOI and BOX layers are limited
                  due to the range and distribution of the implanted ions. Typically, these are ~0.2
                  and ∼0.1 µm, respectively. Wafer bonding is an alternative technique for producing
                  thick layers of silicon on a buried oxide. Two wafers, at least one of which is cov-
                  ered with a thick oxide layer, are bonded together by van der Waals forces, and sub-
                  sequent annealing at ∼1,100°C causes a chemical reaction that strengthens the
                  bonded interface. One of the wafers is then thinned down by mechanical grinding,
                  and a final polish can produce SOI films 1 µm thick with a uniformity of 10% to
                  30%. The BOX layer can be between 0.5 and 4 µm thick. These wafers are some-
                  times referred to as bonded and etched SOI (BESOI) wafers. Both ion implantation
                  and wafer bonding are used in the production of UNIBOND SOI wafers. Starting
                  with two wafers, the silicon surface of one wafer is first oxidized to form what will
                  become the buried oxide layer of the SOI structure. An ion implantation step, using




                                                          Oxidize wafer
                                       +
                            High energy O ion
                            implantation

                            Anneal at 1,300ºC             High energy
                                                           +
                                                          H ion
                                       SIMOX wafers       implantation
                            Oxidized handle               Handle wafer
                            wafer                         bonded on top


                            Bonded to second              Cleave along
                            wafter and annealed           plane
                            at 1,100ºC
                                                          of weakness
                            Ground and polished           Anneal at 1,100ºC
                            device layer                  and polish
                                       BESOI wafers           UNIBOND SOI wafers
                  Figure 2.3  Different manufacturing processes for SOI wafers.
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