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I 10                                                         Heat Treatment of Ferrous Alloys  I I3
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                        0    0_2        0.6   0.8  1_0                   ( 5     “
                               Composition (% C)             .~         5  `  .»  et...
                                    (H)                              (D)
               FIGURE 4.I5  (a) Hardness of martensite as a function of carbon content. (b) Micrograph of
               martensite containing 0.8% carbon. The gray platelike regions are martensite; they have the
               same composition as the original austenite (white regions). Magnification: 1000><.
                   Distortion is an irreversible dimensional change
               of the part during heat treatment. It is a general    70    Initial hardness of martensite
                                                                                     _>
               phenomenon and may consist of size distortion or   6 60           %t=e                go0°C
               shape distortion. Size distortion involves changes in
               the dimensions of the part without a change in shape,  3 50  Ca’b’d@ co T*        T _ ` ` 300°
               whereas shape distortion involves bending, twisting,  <5                _            400 .
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               and similar nonsymmetrical dimensional changes.                "~.       ""5o0°
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               Distortion can be reduced by proper control of heating  § 40    600°
               and cooling cycles, by improved part design, and by
               more localized heat treatment of the part (see also   30      10 min   1 hr    10 hr
               Section 4.13).                                        20
                                                                      102       103        104       105
               Retained Austenite.  If the temperature to which the                     Time (S)
               alloy is quenched is not sufficiently low, only a portion
               of the structure is transformed to martensite. The rest is  FIGURE 4.I6 Hardness of tempered martensite as a function
               retained austenite, which is visible as white areas in the  of tempering time for 1080 steel quenched to 65 HRC.
               structure, along with the dark, needlelike martensite.  Hardness decreases because the carbide particles coalesce and
               Retained austenite can cause dimensional instability  grow in size, thereby increasing the interparticle distance of
               and cracking, and it lowers the hardness and strength  the softer ferrite.
               of the alloy.
               Tempered Martensite.  Martensite is tempered in order to improve its mechanical
               properties. Tempering is a heating process by which hardness is reduced and tough-
               ness is improved. The body-centered tetragonal martensite is heated to an interme-
               diate temperature, typically 15 0°-650°C, where it decomposes to a two-phase
               microstructure consisting of body-centered cubic alpha ferrite and small particles of
               cementite. With increasing tempering time and temperature, the hardness of tem-
               pered martensite decreases (Fig. 4.16). The reason is that the cementite particles co-
               alesce and grow, and the distance between the particles in the soft ferrite matrix
               increases as the less stable and smaller carbide particles dissolve.



               4.1.I Time-Temperature-transformation Diagrams
               Figure 4.17a shows the percentage of austenite transformed into pearlite as a func-
               tion of temperature and time. The transformation from austenite to pearlite (among
               other structures) is best illustrated by Figs. 4.17b and c, in diagrams called isothermal
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