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80  •  Chapter 3    /    The Structure of Crystalline Solids

                                Figure 3.14  For the hexagonal crystal system, the          z
                                (0001), (1011), and (1010)  planes.


                                                                                (1010)
                                                                                                   (1011)




                                                                                 a 3
                                                                                                   a 1
                                                                                      (0001)




                       EXAMPLE PROBLEM 3.13

                         Determination of the Miller–Bravais Indices for a Plane within a
                         Hexagonal Unit Cell
                         Determine the Miller–Bravais indices for the plane shown in the     z
                         hexagonal unit cell.
                                                                                         C = c
                         Solution
                         These indices may be determined in the same manner that was used
                         for the x-y-z coordinate situation and described in Example Problem
                         3.11. However, in this case the a 1 , a 2 , and z axes are used and corre-  a 2  c
                         late, respectively, with the x, y, and z axes of the previous discussion.
                         If we again take A, B, and C to represent intercepts on the respective
                         a 1 , a 2 , and z axes, normalized intercept reciprocals may be written as  a
                                                                                  3
                                                                                                     a
                                               a   a   c                               a
                                                                                                     a 1
                                               A   B   C                                        A = a
                                                                                          B = –a
                         Now, because the three intercepts noted on the above unit cell are
                                       A = a  B = -a  C = c
                         values of h, k, and l, may be determined using Equations 3.14a–3.14c, as follows (assuming n   1):
                                                          na   (1)(a)
                                                        h =  =       = 1
                                                          A      a
                                                          na   (1)(a)
                                                        k =  =       = -1
                                                          B     -a
                                                          nc   (1)(c)
                                                        l =  =      = 1
                                                          C      c
                         And, finally, the value of i is found using Equation 3.15, as follows:
                                                 i = -(h + k) = -[1 + (-1)] = 0
                         Therefore, the (hkil) indices are (1101).
                            Notice that the third index is zero (i.e., its reciprocal    ), which means this plane parallels
                         the a 3  axis. Inspection of the preceding figure shows that this is indeed the case.



                                     This concludes our discussion on crystallographic points, directions, and planes.
                                 A review and summary of these topics is found in Table 3.3.
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