Page 422 - Mechanical Engineers' Handbook (Volume 4)
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3 Thermal Control Techniques  411

                                                                 2
                                                               1
                                                           q   ⁄2IR                           (111b)
                                                            j
                           and minus the heat regained at the cold junction (known as the Fourier heat or Fourier effect)
                           due to the temperature difference 
T   T   T c
                                                            h
                                                     q   K 
T   K(T   T )                     (111c)
                                                      F
                                                                   h
                                                                        c
                           Thus, the net heat absorbed at the cold junction is
                                                                 2
                                                              1
                                                    q    IT   ⁄2IR   K 
T                      (112)
                                                           c
                           where the total resistance of the couple is the series resistance of material A and material B
                           having areas A and A , respectively (both have length L),
                                            B
                                      A
                                                       R     	 A

                                                                  B
                                                             A   A   L                         (113)
                                                              A   B
                           and where the overall conductance K is the parallel conductance of the elements A and B:
                                                          1
                                                      K     (kA   kA )                         (114)
                                                             A
                                                                A
                                                                    B
                                                                      B
                                                          L
                              To power the device, a voltage equal to the sum of the Seebeck voltages at the hot and
                           cold junctions plus the voltage necessary to overcome the resistance drop must be provided:
                                                 V    T    T   RI     
T   RI
                                                            c
                                                       h
                           and the power is
                                                     P   VI   (  
T   RI)I                     (115)
                              The coefficient of performance (COP) is the ratio of the net cooling effect to the power
                           provided:
                                                       q    TI   ⁄2IR   K 
T
                                                                    2
                                                                 1
                                                 COP         c                                 (116)
                                                                       2
                                                       P        
TI   IR
                           Optimizations
                           The maximum possible temperature differential 
T   T   T will occur when there is no
                                                                            c
                                                                       h
                           net heat absorbed at the cold junction:
                                                                1
                                                          
T   ⁄2zT  2 c                       (117)
                                                            m
                           where z is the figure of merit of the material
                                                                  2
                                                            z                                  (118)
                                                               KR
                              The current that yields the maximum amount of heat absorbed at the cold junction can
                           be shown to be 42
                                                                  T
                                                          I   I    c                           (119)
                                                              m
                                                                  R
                           and the coefficient of performance in this case will be
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