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Measurand Modulation

                                                                        Measurand Modulation  227

                       configured for multiple small samples. A track around the perimeter of the
                       50mm diameter paper disk can hold about 50 samples each of 1mL, either all
                       different or multiple instances of the same sample. Two timing mark systems
                       should be provided, one to signal the start of a revolution, the others to signal
                       the angular position around the disk. They can be provided either on the
                       support arbor or printed onto the paper itself. As the disk spins, each sample
                       is read out and the area under the absorption signal is digitized in time. Similar
                       systems have been built based on chemical analyses done in multilayer films in
                       tape form. With a single sample divided into multiple patches and spun at high
                       speed, we effectively have a diffuse reflectance modulated by a periodic modu-
                       lation of sample concentration. Large improvements in LOD are possible with
                       this approach.

           10.7 Remote Sensing: Fiber
           Refractometer Revisited
                       In the modulation techniques described so far, the instrument has been avail-
                       able, and sample modulation has been straightforward in principle. In the case
                       of optical fiber sensors, however, the location where we would like to modulate
                       may be in a remote or inhospitable place. We have already seen the difficulties
                       of achieving even one-bit of resolution in a fiberoptic reflectometer. Due to
                       fiber attenuation which can be highly variable from installation to installation
                       and over time, even detecting the presence or absence of a switched mirror can
                       be difficult. The signal of interest is, because of attenuation, a tiny fraction of
                       the swamping intensity due to unterminated fiber ends, connectors, and mate-
                       rial back-scatter. Modulation of the source, although convenient for intensity
                       quantification and industrial interference removal, does not improve the S/N of
                       the true signal. However, if we can perform the modulation at the distal end of
                       the fiber, that is, of the light incident on the sensor-head, then large improve-
                       ments are possible.
                         Figure 10.15 shows a fiber refractometer with a mechanical intensity modu-
                       lator, formed from a stepper-motor driven chopper wheel. If this is battery-
                       driven, or powered via a solar cell from ambient light or light guided in the fiber,
                       and the power consumption can be kept of the order of 1mW or less, then con-
                       venient and low cost-of-ownership fiber sensors can be constructed. Even micro-
                       electro-mechanical-systems (MEMS) clockwork motors driven by mechanical
                       strain energy may be attractive. With a low-reflection chopper wheel, the signal
                       intensity will change periodically, with the intensity difference being that due
                       to the sensor head reflection. The received signal will contain the disturbing
                       reflections in the unterminated reference fiber arm (9mW), other fiber arms and
                       in-line connectors, with superimposed the small modulated intensity from the
                       liquid under test (minimum 1.5nW). By reducing the detection bandwidth we
                       should have no difficulty in detecting the refractometer signal, with an accu-
                       racy determined by the intensity stability, detector tempco etc. Without the
                       measurand modulation, detection of small changes in the 1.5nW minimum


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