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Polymer nanocomposites for water treatments                       583


              350                                     Fig. 21.12 Nonwoven PANi-PS
                                                      mat adsorption capacity for the
              300                                     different heavy metal ions
                                                      employed.
              250
             q e  (mg/g)  200
              150

              100
               50

                0
                   Pb (II)  Cu (II)  Hg (II)  Cd (II)  Cr (VI)
                             Heavy metal ion



           HFO-802           P −  Phosphate anions      Fig. 21.13 Simultaneous
                                                        adsorption of phosphate and
                   CH 3
                     +                                  p-nitrophenol.
                   NH P −      Electrostatic interaction  Reproduced with the permission
                                                        from Copyright 2015 Elsevier.
                   CH 3
                          P −
                   Fe(OH) n-x OH x  Inner-sphere complexation


                                     p-nitrophenol
                   CH 3
                   N:  HO        NO 2  Acid-base interaction
                   CH 3
                              OH
                                     π-π interaction
                  St-DVB




           21.6.2.1 Dyes
           Organic dyes are used in many industrial processes such as fabric, woven, leather, tex-
           tile, pulp and paper, tanneries, cosmetic, pharmaceuticals, food processing, agricul-
           tural research, electroplating, and distillers. Due to their large-scale production and
           extensive applications, organic dyes have become an integral part of industrial waste-
                           5
           water. Out of 7 10 ton of organic dyes annually produced worldwide, >10%–15%
           is lost in the wastewater during manufacturing and application processes [59]. These
           have adverse effects on the environment particularly inhibitory effect on aquatic
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