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3. NANOMEMS PHYSICS: Quantum Wave Phenomena                   123


                       § p  2     ·
               E η  σ  =  ¨ ¨  − E  F  ¸ η  σ  +  ∆E  σ σ  ζ ,                                          (128a)
                                                σ
                                  ¸
                       ©  2  m    ¹
             and


                        § p  2      ·       *
               -  E ζ  σ  =  ¨ ¨  − E  F  ¸ ζ ¸  σ  +  ∆ E  σ σ  η ,                                     (128b)
                                                   σ
                        ©  2 m      ¹

             is obtained. Solving (128) for E one obtains  E =  ±  ∆  2  +  v 2  (p −  p  ) .
                                                                          2
                                                                 F      F
             This is the dispersion relation for superconducting electrons. It represents a
             parabola with a minimum at  p =  p , corresponding energy  ∆ , and energy
                                            F
             gap  ∆2 . Therefore, application of the Landau criterion for superfluidity, to
             the present case of superconductivity, yields  the critical  velocity,
             v  =  (∆  p  ), below which electron transport experiences  no  electrical
              c       F
             resistance, i.e., is superconductive. Next, we address the formation of Cooper
             pairs.
               In   exploiting  the  superfluid  physics  analogy  to  describe
             superconductivity, one must confront the issue of explaining how electrons,
             which would ordinarily be precluded  from  binding, due  to  Coulomb’s
             repulsion  force,  would  bond/condense to  form bosons. The clue to this
             possibility  was  advanced by the discovery that  [157],  [158] in
             superconducting  elements,  the product of the square root of their isotopic
             mass and the critical temperature,  M  2 / 1  T , is a constant. This experimental
                                                c
             fact, in turn, was interpreted by Fröhlich [154] to mean that the properties of
             the zero-point or thermal lattice phonons, were involved  in
             superconductivity and, in particular, that electrons residing within the crystal
             lattice were capable,  via interactions mediated  by  these phonons, of
             attracting one another. This phenomenon is demonstrated next.
               To  determine the nature of the  phonon-mediated electron-electron
             interaction, we assume the coexistence of phonons and electrons is described
             by  a Hamiltonian consisting of three  terms, namely,  the energy of the
             electrons, the energy of the phonons, and the energy of interaction between
             electrons and phonons, respectively. The first two terms are captured by the
             “unperturbed” Hamiltonian:

               H   = ¦   E G  c +  c G  + ¦ = ω a GG  + a G
                              G
                  0        σ , k  σ , k  σ , k  q  q  q .                                          (129)
                      G                G
                       σ , k           q
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