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3. NANOMEMS PHYSICS: Quantum Wave Phenomena                   125

             contains  no off-diagonal terms of  O(D). In particular, if we  take
             H =  H +  H , where  H  gives rise to the solutions  n  when  H = , so
                                                                       '
                        '
                                                                          0
                   0
                                  0
                                    ~
             that H  n =  E  n , then H  may be expanded as, [131],
                   0      n
                                                        §
             ~
             H =  e − S (H +  H ' )e =  § 1 ¨ − S +  S 2  +  ...¸ · (H +  H ' ) 1 ¨ + S +  S 2  +  ...¸ ·
                              S
                       0         ¨             ¸  0     ¨             ¸
                                 ©       2     ¹        ©       2     ¹
                =  H +  [ S,H  ]+  1  [ [ ,H  ] ] ...S, S  +           .    (136)
                             2
                =  H +  H +  [H  S ,  ] [H ++  1  '  [H  ] ] [ ,HS, S ,  +  1  '  S ] ...+
                         '
                    0         0             0
                                   2                2

             If we select  H +  [H  0  S ,  ] 0= ,  then the  second and third terms  in (136)
                           '
             vanish and we have a prescription for S, namely,
                                                            n '  H '  n
                n '  H '  n + (E −  E  ) n '  S  n =  0 Ÿ  n '  S  n =  ,          (137)
                            n  '  n                        E −  E
                                                             n '  n

             which yields the desired Hamiltonian as,

                ~
               H =  H +  1  [ ,H '  S +  O  S 2
                               ] ().                                                                 (138)
                     0
                         2
             Now, in this diagonal formulation, effective electron-electron interaction is
                                                                    '
             elucidated by considering the case in which the perturbation  H  causes the
             following transitions: Either the electron in state k emits a phonon –q and
             this is absorbed by the electron in state k’, or the electron in state k’ emits a
             phonon q and this is absorbed by the electron in state k. These transitions
             may be mathematically represented as occurring from an initial state  i  to a
             final state  f  via  a virtual state  m , in terms  of which the expectation
             value of the commutator in (138) may be expressed as,

                f  [ H,S  '  ]i  =  ¦ ( Sf  m  m  H '  i  − f  H '  m  m  S  ) i .                  (139)
                            m
             Following [154], consideration of the phonon system at absolute zero, so that
             one of the phonon states refers to the vacuum, the matrix element calculation
             (134) over the phonon operators yields, without loss of generality,
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