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Batteries and Ultracapacitors for Electric Power Systems with Renewable Energy Sources   329


                                                   C ss  R ss


                                      +                       +
                                                     R s
                                          C o              Terminal
                                       OCV   R sd           voltage
                                      –                       –

            FIGURE 13.9  Electric equivalent circuit model for an ultracapacitor. (Based on the concept proposed in
            Manla, E. et al., Proceedings of Energy Conversion Congress and Exposition (ECCE), pp. 2957–2962, 2011.)


            response of an ultracapacitor. The parameter identification requires multiple AC and DC tests. The
            equivalent incremental internal capacitance is calculated as

                                      0 (
                                                            i
                                     COCV i) =   ∆ Q i ∑   i It ()∆ t                 (13.4)
                                                      =
                                                ∆ OCV i   ∆ OCV i
            where
              OCV is the open-circuit voltage
              I is the current
              Q is the columbic charge for the data point i
              It should be noted that a columbic counting technique has been employed to estimate the SOC,
            which varies approximately linearly with OCV.
              An 1100 F Li-ion ultracapacitor was charged during 16 cycles in which each cycle consists
            of 10 s charging and then rest (disconnected from the source) for 20 s. Figure 13.10 verifies the
            accuracy of the equivalent circuit model of Figure 13.9 by comparing the terminal voltage of the
            ultracapacitor and the simulation model.
              Some models that combine equivalent circuits and electrochemistry fundamentals have also been
            proposed [31, 32]. Yet in another approach, training data represented by the voltage, current, and
            temperature values measured during charging and discharging experiments have been used to train
            a neural network [37].


                                   4
                                               Simulation
                                 3.5           Test
                                Voltage (V)  3



                                 2.5


                                   0
                                    0   60  120  180  240  300  360  420  480
                                                   Time (s)

            FIGURE 13.10  Experimental data and simulation results for a Li-ion ultracapacitor, 10 A pulsed charg-
            ing DC test at 25 °C. (Based on the concept proposed in Manla, E. et al., Proceedings of Energy Conversion
            Congress and Exposition (ECCE), pp. 2957–2962, 2011.)
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