Page 194 - Reservoir Formation Damage
P. 194

176   Reservoir Formation Damage

                  Scale  Formation   and  Dissolution   at  the  Pore  Surface

                  The  rate  of  scale  formation  at  the  pore  surface  can  be  expressed
               similarly  to  crystal  growth.  The  pore  volume  relates  to  the  diameter  of
               an  equivalent  spherical  shape  pore  space  by  (Civan,  1996):

                                                                           (9-30)


               indicating  that






               Thus,  the  pore  surface  relates  to  the  porosity  according  to:

                                    2/3
                                                                          (9-32)

                                                                3
                   and     are  some  shape  factors  and  C 5=C 4/C^ .  The  porosity  of
                C 3    C 4
               the  solid  porous  matrix  can  be  expressed  as  a  sum  of  the  instantaneous
               porosity,  <|>,  and  the  pore  space  occupied  by  the  scales,  <{> 5,  as:

                  4>r=4> +  <l>,                                           (9-33)

               Therefore,  the  mass  of  the  scale  formed  over  the  pore  surface  is  given  by


                     = PA =                                               (9-34)

               Therefore,  substituting Eqs.  9-32 and 9-34 into  Eq. 9-23 yields  (Civan,
                1996):



                                                                          (9-35)


               subject  to

                                                                          (9-36)


               where
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