Page 38 - Reservoir Formation Damage
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22   Reservoir Formation Damage

                  3.  Also,  fines  attached  to  swelling  clays  can  be  dislodged  and  liber-
                     ated  during  clay  swelling,  the  phenomenon  of  which  is  referred  to
                     as  fines  generation  by  discontinuous  jumps  or  microquakes  by
                     Mohan  and  Fogler  (1997).

                  Consequently,  formation  damage  occurs  in  two  ways:  (1)  the  perme-
                ability  of  porous  formation  decreases  by  reduction  of  porosity  by  clay
                swelling  (Civan  and  Knapp,  1987; Civan  et  al.,  1989; and  Mohan  and
                Fogler,  1997);  and  (2)  the  particles  entrained  by  the  flowing  fluid  are
                carried  towards  the pore  throats  and captured by  a jamming  process.  Thus,
                the  permeability  decreases  by  plugging  of  pore  throats  (Sharma  and
                Yorstos,  1983;  Wojtanowicz et  al.,  1987, 1988;  Mohan  and  Fogler,  1997).
                  Khilar  and  Fogler  (1983)  have  demonstrated  by  the  flow  of  aqueous
                solutions  through  Berea  sandstone  cores  that  there  is  a  "critical  salt con-
                centration  (CSC)"  of  the  aqueous  solution  below  which  colloidally  in-
                duced  mobilization  of  clay  particles  is  initiated  and  the  permeability  of
                the  core  gradually  decreases.  This  is  a result  of  the  expulsion  of  kaolin-
                ite particles  from  the pore  surface  due  to the  increase  of the  double-layer
                repulsion  at  low  salt  concentration  (Mohan  and  Fogler,  1997).  The  criti-
                cal  salt  concentrations  for  typical  sandstones  are  given  by  Mohan  and
                Fogler  (1997)  in  Table  2-3.

                                Mechanism     of  Clay  Swelling

                  A  structural model  of  swelling clays having exchangeable  cations,  de-
                          z+
                noted  by M , is shown by Zhou  et  al.  (1996,  1997)  in Figure 2-12. Zhou
                et al  (1996)  states:  "The structure  layers  are  always  deficient  in  positive
                charges  due  to  cation  substitution,  and  interlayer  cations  are  required  to
                balance  the negative layer  charge.  Interlayer  cations  are exchangeable  and
                the  exchange  is  reversible  for  simple  cations.  The  distance  between  two




                                            Table 2-3
                          Critical Salt Concentrations in Typical  Sandstone

                                          Stevens                  Berea
                Salt                         M                       M
                NaCl                      0.50-0.25                 0.07
                KC1                        0.3-0.2                  0.03
                CaCL                       0.3-0.2                 None
                *  After Mohan, K. K., and Fogler, H. S., ©1997; reprinted by permission of the AIChE, ©1997 AIChE. All
                 rights reserved.
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