Page 40 - Reservoir Formation Damage
P. 40

24    Reservoir Formation Damage

                   Mohan  and  Fogler  (1997)  conclude  that  crystalline swelling  occurs  at
                high  concentrations  below  the  critical  salt  concentration  and  osmotic
                swelling  occurs  at  low  concentrations  above  the  critical  salt  concentra-
                tions.  Mohan  and  Fogler  (1997)  measured  the  interplanar  spacing  as  an
                indication  of  swelling  of  montmorillonite in  various  salt  solutions.  Thus,
                according  to Figures  2-13 and  2-14  given  by Mohan  and Fogler  (1997),
                the  crystalline  and  osmotic  swelling  regions  can  be  distinguished  by  a
                sudden jump or discontinuity in the value of the interplanar spacing which
                occurs  at  the  critical  salt  concentration.

                              200.0-
                                     o  Swy-1 - Norrish
                                     •  Stevens - This Work
                           g>  150.0-  D  Swy-2- This Work
                           "o
                           <J  100.0 Crystalline Swelling
                           CB
                                                       Osmotic Swelling
                           J5
                           &  50.0-             Critical Salt
                                                Concentration
                               0.0
                                                                 10


                Figure  2-13.  Swelling  of  montmorillonite in  sodium  chloride  brine  (after
                Mohan,  K.  K.,  and  Fogler,  H. S., ©1997;  reprinted by permission  of  the AlChE,
                ©1997  AlChE.  All  rights  reserved).

                            100.0 -

                          '<,  80.0  -
                           O)
                           £
                           a  60.0 H
                           (A
                           l_
                           (0  40.0  -
                           c
                           S-  20.0 H

                              0.0
                                     0.5  1  1.5              3.5

                Figure  2-14.  Swelling  of  montmorillonite  in  various  brine  (after  Mohan,
                K.  K.,  and  Fogler, H. S., ©1997;  reprinted  by permission of the AlChE, ©1997
                AlChE. All  rights  reserved).
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