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From Global Balance to Local Non-Equilibrium
                                                            d
                                   d
                                                              j
                                                (
                               qD ---- Bu ([
                                                              [
                                                                         (
                                                  kj
                                                                           ki
                                  ni
                                            i
                                                                              k
                                                     k
                                                           nj
                                                                     i
                                                            L
                                   L i   jk )n –  Bu )n ] +  qD ----- Bu (  ik )n –  Bu )n ]
                                    i                         j
                                                                                  (6.98)
                                                     d L +  d L j
                                                       i i
                                                            j
                                                =  qR --------------------------
                                                     k
                                                         2
                             Here we used  D   and  D   as the values of the diffusion coefficient
                                           ni      nj
                             along the edges   and  .  j R   is the value of the recombination rate at
                                          i
                                                    k
                             node  . For inhomogeneous materials these values have to be deter-
                                  k
                             mined by appropriate averaged values. The same equation as (6.98) holds
                             for the defect electron with the restriction that all   have to be replaced
                                                                     n
                                                u
                             by   and the indices at   have to be reversed.
                               p
                             6.3.4 Kinetic Theory and Methods for Solving the BTE
                             The term kinetic theory means that a description of the system is given
                             where no assumptions about the distribution function are made. There is
                             no parametrization by a few parameters, e.g., the temperature. Moreover,
                             the non-equilibrium situation could even prohibit a definition of parame-
                             ters like the temperature. This implies that a full solution of the Boltz-
                             mann transport equation must be obtained. There are several methods to
                             solve this task that require more or less computational effort and lead to
                             more or less accurate results. In the following we shall discuss four of
                             them.
                Iterative    The iterative method makes use of a transformation of the BTE into an
                Method       integral equation. Write (6.2) in the form
                                df  k  ∂f  k       —k
                                                                            f )
                                    =    – qE∇ f +  ------∇ f  =  – ∑ ( W kk' k  W k'k k'
                                                                     f –
                                              k k
                                                       x k
                                 t d   t ∂         m
                                                              k'                  (6.99)
                                                               
                                                   k k ∑
                                             =   – Γ f +  W   f
                                                           k'k k' 
                                                        k'
                             where we used
                                              ˙
                                                  ----------
                                             k =  – qE   and x ˙ =  —k           (6.100)
                                                              ------
                                                   —          m
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