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Crystal Structure
                Box 2.1. Plane waves and wave-vectors.
                 We describe a general plane wave with  counts the number cycles completed along a spa-
                                (
                                i kr ωt)             tial segment.
                                  ⋅
                                   –
                        (
                         ,
                       ψ r t) =  Ae   .     (B 2.1.1)
                                                     If we fix the time t (“freezing” the wave in space
                 Recalling the relation between the trigonometric
                                                     and time), then moving along a spatial direction
                 functions and the exponential function,
                                                     we will experience a wave-like variation of the
                       iθ
                      e  =  cos  θ () +  i sin  θ ()  .  (B 2.1.2)  amplitude of ψ   as kr⋅  . If we now move in a
                 we see that ψ   is indeed a wave-like function, for   direction perpendicular to the propagation of the
                 θ   parametrizes an endless circular cycle on the   wave  , then we will experience no amplitude
                                                         k
                 complex plane.                      modulation. Next, staying in the perpendicular
                                                     direction to the wave propagation at a fixed posi-
                          I      iθ
                                e                    tion, if the time is again allowed to vary, we will
                                                     now experience an amplitude modulation as the
                                                     wave moves past us.
                              θ
                                        R
                   Figure B2.1.1: The exponential function
                   describes a cycle in the complex plane.
                                                                                   x
                 Equation (B 2.1.1) is a powerful way of describing
                 a plane wave. Two vectors, the spatial position
                 vector   and the wave vector, or reciprocal posi-
                      r
                 tion vector  , are position arguments to the expo-
                         k
                 nential function. The cyclic angle that it the wave
                 has rotated through is the complete factor
                                                                      t
                   ⋅
                 ( kr ωt)  . Since   measures the distance along
                     –
                              r
                                                       Figure B2.1.2: The appearance of a 1-
                                       k
                 an arbitrary spatial direction and   points along
                                                       dimensional wave plotted for t and x as
                 the propagation direction of the wave, kr⋅   gives   parameters. If t is kept stationary, moving in the
                                                       x-direction is accompanied by a wave-like
                 the component of this parametric angle.   mea-
                                           k
                                                       variation.
                 sures rotation angle per distance travelled (a full
                 cycle of 2π   is one wavelength), so that kr⋅
                             ces are the components of a  -space vector (the vector is normal to the
                                                    k
                             plane) that fulfil kr⋅  =  Constant  , where   lies on the plane of interest.
                                                               r
                             As an example, consider a cubic lattice with the Miller indices  mn p,,(  )
                             of a plane that lies parallel to a face of the cube. The indices determine
                                            k
                             the plane-normal  -space vector  k =  mb +  nb +  pb  .  The plane is
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