Page 250 - Separation process engineering
P. 250

Figure 6-2. Distillation column for matrix analysis


























                                                           Figure 6-3. General stage in column























                    The unknown vapor compositions, y  and y         i.j+1 , can be replaced using the equilibrium expressions
                                                             i,j



                                                                                                                                  (6-2)

                    where the K values depend on T and p. If we also replace x  and x           i,j-1  with
                                                                                        i,j



                                                                                                                              (6-3a,b)


                    where   and      i,j-1  are the liquid component flow rates, we obtain
                             i,j





                                                                                                                                  (6-4)

                    For each component, this equation can be written in the general form




                                                                                                                                  (6-5)

                    The constants A, B, C, and D are easily determined by comparing Eqs. (6-4) and (6-5).
                                          j
                                      j
                                                      j
                                              j
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