Page 152 - The Tribology Handbook
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A27          Bearing surface treatments and coatings




              Table 27.4  Diffusion of materials into surfaces

              PTOCeSS                  Mechanism              Surface eflects          De@  aspects
              Carburising of steels    Carbon is diffused into the   Hard surfaces at depths up to   Suitable, for example, for gears
                                        surface at temperatures   several mm depending on   to increase surface fatigue
                                        around 900°C followed by   the diffusion time.   strength or pump parts to
                                        quenching and tempering   Dimensional changes of   increase abrasive wear
                                                                +. 0.1 % may occur      resistance

              Carbonitriding of steels   Similar to carburising but with   Slightly harder surfaces are   Can be oil quenched with
                                        addition of nitrogen as well   obtainable       some reduction in distortion
                                        as carbon                                       of the component
              Boronising of steels     Diffusion of boron into the   Surface hardiiesses up to 1200   The core material needs to be
                                        surface to form iron boride   Hv                relatively hard to support
                                                                                        the surface layer

              Vanadium, niobium or     Salt bath treatment at 1020°C   Layer hardness up to 3500 Hv   Used to reduce wear of the
                chromium diffusion into   to produce thin surface   at up to  15 pm thickness   surfaces of metal forming
                steels                  layers of the metallic carbide                   tools
              Chromising, aluminising and   High temperature pack   Increased surface hardness   Improves high temperature
                siliconising of steels   processes for diffusing these                  corrosion resistance and
                                        materials into the surface                      reduces fretting damage

              Nitriding of steels which   Treatment at about 550°C in   Hardness up to 850 Hv with   Forms a brittle white surface
                contain chromium or     cracked ammonia gas or   surface layers up to 0.3 mm   layer which needs to be
                aluminium               cyanide salt bath to produce   deep             removed before use in
                                        chromium or aluminium                            tribological applications
                                        nitrides in the surface layers
              Nitrocarburising of steels   Salt bath, gas or plasma   Hard surface layer about 20   Reduces fretting damage. The
                including plain carbon steels   treatments are available   pn thick with hardness of   surface layer can be oxidised
                (tufftriding)                                   about 700 Hv             and impregnated with
                                                                                         lubricant to produce a low
                                                                                         friction corrosion resistant
                                                                                         surface
              Ion implantation of steel   Surface bombardment by  a   Surface effects to a depth of   Can improve resistance to
                                         high energy nitrogen ion   0.1  Frn             abrasion and fatigue
                                         beam at 150°C produces up
                                         to 30% implanted material
                                         at the surface
               Sulfinuz treatment of steel   Salt bath  treatment at about   Surface layer contains   Can give improved  scuffing
                                         600°C  to add carbon,   sulphides which  act as a   resistance with little risk of
                                         nitrogen and sulphur    solid lubricant in the surface   component distortion during
                                                                                         treatment

               Phosphating of steel    Phosphate layer produced by   Surface layer which is porous   Assists running in and reduces
                                         chemical or electrochemical   and helps to retain lubricant   risk of scuffing
                                         action
               Electrolytic deposition and   Copper, aluminium and   Creates surface layers at   Gives improved scuffing and
                diffusion  of material into   titanium can be treated at   selected positions   wear resistance
                non-ferrous metals       temperatures in the range
                                         200-400"c
               Hard anodising of aluminium   The component is made the   The hard layer is usually   The coating is porous and can
                                         anode for electrolytic   25-75  pm thick        be overlaid with PTFE to
                                         treatment in sulphuric acid.                    to give a low friction surface
                                         The oxygen generated at the
                                         surface produces a hard
                                         porous oxide layer







                                                           A27.3
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