Page 312 - Thermodynamics of Biochemical Reactions

312 Mathematica Solutions to Problems

PH 5 PH 6 PH 7 PH 8 PH 9
I=OM 11.3123 9.42916 6.0856 4.60067 1.48513
I = 0.10 M 8.64828 5.44782 2.53412 0.710067 -3.18751

I = 0.25 M 7.58697 4.09308 1.26214 -0.651704 -4.72216
TableForm[Transpose[calckgrime[succinylcoA+gi+adg+de==succinate+atg+coA,{5,6,7,8,9~,{0,
.1,.25)]],TableHeadings->{{~'I = 0 M","I = 0.10 M","I = 0.25 M"),{"pH 5","gH 6","gH
7","gH 8","gH 9")}]
PH 5 PH 6 PH 7 PH 8 PH 9
I=OM 0.0104276 0.0222891 0.0858727 0.156315 0.549312
I = 0.10 M 0.0305419 0.111068 0.359786 0.750935 3.61763
I = 0.25 M 0.0468627 0.191835 0.601012 1.30069 6.71864

TableForm[(1/(8.3145l*.298l5*Log[lOl))*D[(succinate+atg+coA-succ~nylcoA-p~-
adg),gH]/.is->{O, .l, .25}/.pH->{5,6,7,8,9},TableHeadings->{{*'I = 0 M","I = 0.10 M","I =
0.25 M1m},{tlpH 511,11pH 611,11gH 711,1tpH 8","gH 911))1
PH 5 PH 6 PH 7 PH 8 PH 9
I=OM -0.0431903 -0.591126 -0.421843 -0.27808 -0.799126
I = 0.10 M -0.347965 -0.659794 -0.328911 -0.443368 -0.876329
I 0.25 M -0.436744 -0.660859 -0.321521 -0.47926 -0.892712

Succinate dehydrogenase

TableForm[Trans~ose[calctrGerx[succinate+fadenzox+de==fumarate+fadenzred,~5,6,7,8,9~,~O
,.1,.25}]],TableHeadings->{{"I = 0 M",811 = 0.10 M","I = 0.25 M1r),{"gH 5","pH 6","pH
7","pH 8","gH 9"}}1
PH 5 PH 6 PH 7 PH 8 PH 9
I=OM 3.58609 0.778578 0.0656228 -0.0202505 -0.0290231
I = 0.10 M 2.15463 0.30828 0.00611379 -0.0263635 -0.0296361
I = 0.25 M 1.7504 0.220992 -0.00368738 -0.0273557 -0.0297354

TableForm[Transgose[calckprime[succinate+fadenzox+de==fumarate+fadenzred,{5,6,7,8,9~,~O
=
,.1,.25)]],TableHeadings->{(8tI = 0 M1m,lmI 0.10 M","I = 0.25 M"},{"pH 5","gH 6","pH
71*,11gH 811,11pH 9")}]
PH 5 PH 6 PH 7 PH 8 PH 9
I=OM 0.235369 0.730466 0.973876 1.0082 1.01178
I = 0.10 M 0.419303 0.883064 0.997537 1.01069 1.01203
I = 0.25 M 0.493565 0.914711 1.00149 1.0111 1.01207

TableForm[(1/(8.31451*.29815*Log[1O]))*D[(fumarate+fadenzred-succ~nate-
fadenzox),pH]/.is->{O,.l,.25}/.gH->{5,6,7,8,9},TableHeadings->{{~~I = 0 M","I = 0.10
M","I = 0.25 M"},{"gH 5","pH 6","pH 7","pH 8","pH 9"))l
PH 5 PH 6 PH 7 PH 8 PH 9
I=OM -0.658653 -0.272415 -0.0377549 -0.00392427 -0.000393977
I = 0.10 M -0.565671 -0.127042 -0.0144565 -0.0014658 -0.000146785
I = 0.25 M -0.504786 -0.0961348 -0.0105565 -0.00106609 -0.000106714

Fumarase