Page 310 - Thermodynamics of Biochemical Reactions

310 Mathernatica Solutions to Problems

PH 5 PH 6 PH 7 PH 8 PH 9
I=OM 0.000858528 0.00946228 0.0273705 0.033346 0.034086

I = 0.10 M 0.00437581 0.0217167 0.0323499 0.0339794 0.034151
I = 0.25 M 0.0068089 0.025247 0.0330192 0.0340517 0.0341583
TableForm[(1/(8.3145l*.298l5*Log[lO]))*D[(aconitatec~s+h2o-c~trate),gHl/.~s-
>{0,.1,.25}/.pH->{5,6,7,%,9},TableHeadings->{{'1I = 0 M1l,"I = 0.10 M","I = 0.25
M"},{iipH 5'*,''pH 6tv,11gH 7'm,11gH 8",11pH 9m1}}1
PH 5 PH 6 PH 7 PH 8 PH 9
I=OM -1.32911 -0.762126 -0.200124 -0.0241339 -0.00246441
I = 0.10 M -1.02481 -0.372043 -0.0533865 -0.0055862 -0.000561228

I = 0.25 M -0.907921 -0.265114 -0.0337371 -0.00346956 -0.000347946
Aconitase

TableForm[Transgose[calctrGerx[aconitatecis+h2o+de==c~trateiso,{5,6,7,8,9~,{O,.l,.25~ll
,TableHeadings->{{liI = 0 M","I = 0.10 M","I = 0.25 M"},{mlgH 5","gH 6","pH 7m1,"pH
8","gH 911}}1
PH 5 PH 6 PH 7 PH 8 PH 9
I=OM -10.8055 -4.92275 -2.27779 -1.7815 -1.72622
I = 0.10 M -6.81316 -2.85648 -1.85783 -1.73411 -1.72141

I = 0.25 M -5.72527 -2.4798 -1.80629 -1.72875 -1.72088
TableForm[:Trans~ose[calckprime[acon~tatec~s+h2o+de==c~trate~so,~5,6,7,8,9~,~O,.1,.25}11
,TableHeadings->{{"I = 0 M","I = 0.10 M","I = 0.25 M"},{"gH 5","pH 6","gH 7","gH
8","gH 9"))J
PH 5 PH 6 PH 7 PH 8 PH 9
I=OM 78.1691 7.28489 2.5064 2.05165 2.0064
I = 0.10 M 15.6173 3.16542 2.11581 2.0128 2.00252

I = 0.25 M 10.0697 2.71919 2.07227 2.00846 2.00209
TableForm[(1/(8.3145l*.298l5*Log[lO]))*D[~citrateiso-aconitatecis-h2o~,~H~ /.is-
>C0,.1,.25}/.pH->{5,6,7,8,9),TableHeadings->{{11I = 0 Mnl,"I = 0.10 M","I = 0.25
M" 1, C "pH 5", "pH 6", "pH 7", "pH 8", l'pH 9") 1 I
PH 5 PH 6 PH 7 PH 8 PH 9
I=OM 1.30605 0.760857 0.202526 0.0245142 0.00250437
I = 0.10 M 1.0124 0.374671 0.0541865 0.00567633 0.00057035

I = 0.25 M 0.899474 0.267618 0.0342572 0.00352569 0.000353603
Isocitrate dehydrogenase

TableFo~[Transpose[calctrGerx[:citrateiso+nadox+h2o+de==ketoglutarate+co2tot+nadred,~5,
6,7,8,9},{0,.1,.25}]],Tab1eHeadings->{{'11 = 0 M","I = 0.10 M","I = 0.25 M"},{"gH
5","pH 6**,"gH 7**,"pH 8",11pH 9v1)>1
PH 5 PH 6 PH 7 PH 8 PH 9
I=OM 8.34114 1.67592 -4.21769 -9.97115 -15.7852
I = 0.10 M 5.50847 0.398237 -4.45015 -10.0157 -15.9678
I = 0.25 M 4.78775 0.245626 -4.45696 -10.0274 -16.0697