Page 492 - Bird R.B. Transport phenomena
P. 492

472   Chapter 15  Macroscopic Balances for Nonisothermal Systems

                              We  next eliminate ^) and (v ) from  the above  two equations to get an expression  for the
                                                      2
                           mass  flow rate:

                                                              -2a 2  Г  (l/p)dp
                                                w  =  p 2 S 2                                 (15.5-32)
                                                          -  (a 2 /'a ] )(p 2 S 2 /PiS]) 2  +  a 2 e v

                                                                                                     2
                           We  now  repeat the assumptions  of Example  7.6-5: (i) e  = 0, (ii) a }  = 1, and (iii) a 2  =  (S /S ) .
                                                                      v
                                                                                                  0
                                                                                                    2
                           Then  Eq. 15.5-32  becomes
                                                                -2  \ (l/p)dp
                                                     w  =  C d p 2 S 0 .                       (15.5-33)
                                                               1  -
                           The empirical  "discharge  coefficient/'  C , is included in this equation to permit correction of
                                                           d
                           this  expression  for errors  introduced by the three assumptions  and  must be determined ex-
                           perimentally.
                               For Venturi meters, it is convenient to put plane 2 at the point of minimum cross section of
                           the meter so that S  = S . Then a  is very  nearly  unity, and it has been  found  experimentally
                                                     2
                                              o
                                          2
                           that C  is almost the same for compressible  and incompressible  fluids—that  is, about  0.98 for
                                d
                           well  designed  Venturi  meters.  For orifice  meters, the degree  of contraction of a  compressible
                           fluid  stream at plane 2 is somewhat less than for incompressible  fluids,  especially  at high  flow
                           rates, and a different  discharge  coefficient 2  is required.
                               In  order to use Eq.  15.5-33, the fluid  density  must be known  as a function  of pressure.
                           That is, one must know  both the path of the expansion  and the equation of state of the  fluid.
                           In most cases  the assumption  of frictionless  adiabatic behavior  appears to be acceptable. For
                                                    y
                           ideal  gases, one may write  pp~  = constant, where у = C /C v  (see  Eq. 15.2-5). Then Eq. 15.5-
                                                                         p
                           33 becomes
                                            w  = C p S {                                      (15.5-34)
                                                   2
                                                 d
                                                                        2
                                                               -    (S /S,) (p / ) 2/y
                                                                     0    2 Pl
                           This formula  expresses  the mass  flow  rate as a function  of measurable  quantities and the dis-
                           charge coefficient.  Values of the latter may be found in engineering handbooks. 2
       EXAMPLE  15.5-4     A compressible  gas,  initially at T = T , p = p , and p = p , is discharged  from a large  station-
                                                         o
                                                               0
                                                                        0
                           ary  insulated  tank through a small  convergent  nozzle, as shown in Fig. 15.5-6. Show how the
     Free Batch  Expansion  fractional  remaining mass  of fluid  in the tank, p/p ,  may be determined as a function  of time.
                                                                   0
     of a Compressible Fluid  Develop working  equations, assuming  that the gas is ideal.
     SOLUTION              For  convenience, we divide  the tank into two parts, separated  by the  surface  1 as shown in
                           the figure.  We assume  that surface  1 is near enough to the tank exit  that essentially  all of the
                           fluid  mass is to left  of it, but far enough  from  the exit  that the fluid  velocity  through the sur-
                           face  1 is negligible.  We further  assume  that the average  fluid  properties  to the left  of 1  are
                           identical with  those at surface  1. We now consider  the behavior  of these two parts  of the sys-
                           tem  separately.
                           (a)  The bulk of the fluid in the tank.  For the region to the left  of surface  1, the unsteady  state
                           mass balance in Eq. (A) of Table  15.5-1 is
                                                          4-(piV)=  -W,                        (15.5-35)


                               2
                                R. H. Perry, D. W. Green, and J. O. Maloney, Chemical Engineers' Handbook, 7th Edition,
                           McGraw-Hill, New  York  (1997); see also, Chapter 15 of Handbook of Fluid Dynamics  and Fluid  Machinery
                           (J. A. Schertz and A. E. Fuhs, eds.), Wiley, New  York  (1996).
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