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§15.5  Use of the Macroscopic Balances to Solve Unsteady-State Problems  467

                           heating coil, and the overall  heat transfer  coefficient  is  100 Btu/hr •  ft 2  •  F. What  is the temper-
                           ature of the water when the tank is  filled?


     SOLUTION              We  shall make the following  assumptions:
                               a.  The steam temperature is uniform throughout the coil.
                              b.  The density and heat capacity do not change very much with temperature.
                               с  The fluid  is approximately incompressible  so that C p  ~  C .
                                                                              v
                              d.  The agitator maintains uniform temperature throughout the liquid.
                               e.  The heat transfer  coefficient  is independent of position and time.
                               f.  The walls of the tank are perfectly  insulated so that no heat loss occurs.

                              We  select the fluid  within the tank as the system  to be considered, and we  make a time-
                           dependent  energy  balance over  this  system.  Such a balance  is  provided  by  Eq.  (E) of  Table
                           15.5-1. On the left  side  of the equation the time rates  of  change  of  kinetic and potential ener-
                           gies can be neglected relative to that of the internal energy. On the right side we  can normally
                           omit the work  term, and the kinetic and potential energy  terms can be discarded, since they
                           will be  small  compared with  the other terms. Inasmuch as there is no outlet stream, we  can
                           set w  equal to zero. Hence for this system  the total energy  balance simplifies  to
                               2
                                                         j  tf  = w,H, + Q                     (15.5-1)
                                                         t  tot
                           This states that the internal energy  of the system  increases because  of the enthalpy added  by
                           the incoming fluid, and because  of the addition of heat through the steam coil.
                              Since (i  and H^ cannot be^given  absolutely,  we  now  select  the inlet temperature  7^ as
                                     tot
                           the thermal datum plane. Then H  = 0 and  L7  = pC V(T  -  TO ~ pC V{T -  T ), where T and
                                                     }         tot   v            p      }
                           V  are the instantaneous temperature and volume  of the liquid. Furthermore, the rate  of heat
                           addition to the liquid  Q  is  given  by  Q  =  UQA(T  -  T), in which  T  is the steam temperature,
                                                                 S              s
                           and A is the instantaneous heat transfer  area. Hence Eq. 15.5-1 becomes
                                                    C  j  V(T -  TO = UoA(T, -  T)             (15.5-2)
                                                    P  p

                           The expressions  for  V(t) and A(t) are

                                                 V(t)  = ^ t  A(t)  = — A o  = —jj- A o        (15.5-3)
                                                      -
                           in which  V  and A  are the volume and heat transfer  area when the tank is  full.  Hence the en-
                                    o    o
                           ergy balance equation becomes
                                           w t t  j-AT-  TO + w,C (T  -T0  = ^r  UoA (T, -  T)  (15.5-4)
                                                                              Q
                                                              p
                                             x p
                                              h               y
                                                at                     pv 0
                           which is to be solved  with the initial condition that T = T  at t = 0.
                                                                        }
                               The  equation  is  more  easily  solved  in  dimensionless  form.  We  divide  both  sides  by
                           w,C (T  -  T,) to get
                              p  s
                                                                                               (15.5-5)
                           This equation suggests that suitable definitions  of dimensionless temperature and time are

                                                                and  x = ^                    (15.5-6,7)
                                                                         pC p V 0
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