Page 488 - Bird R.B. Transport phenomena
P. 488

468  Chapter 15  Macroscopic Balances  for Nonisothermal Systems


                              1.0                                    Fig. 15.5-2.  Plot of dimensionless  temper-
                                                                     ature, 0  = (T -  TJ/(T,  -  7V, versus
                              0.9                                    dimensionless  time, т = (UoA /pC V )t,
                                                                                                 0
                                                                                                p
                                                                                            0
                              0.8                                    according to Eq. 15.5-10.  [W.  R. Marshall
                                                                     and  R. L. Pigford,  Application of Differen-
                              0.7                                    tial Equations  to Chemical Engineering, Uni-
                                        /
                              0.6                                    versity  of Delaware Press, Newark, Del.
                                                                     (1947), p. 18.]
                            0  0.5
                                    /
                              0.4
                                    f
                              0.3
                                  /
                              0.2
                                 /
                              0.1
                                /
                                0  1                   7  8   9  10


                            Then the equation in Eq. 15.5-5 becomes after  some  rearranging

                                                                                                (15.5-8)

                            and the initial condition requires that 0  = 0 at r  = 0.
                               This is a first-order  linear differential  equation whose  solution is  (see Eq. C.I-2)
                                                                   -  Ce
                                                          6  = 1  -                             (15.5-9)
                            The constant  of  integration, C, can be obtained  from  the initial condition after  first  multiply-
                            ing Eq. 15.5-9 by  т. In that way  it is found  that С = 1, so that the final  solution is

                                                           0  = 1  -  1  - e~                  (15.5-10)

                            This function  is shown  in Fig. 15.5-2.
                               Finally, the temperature T  of  the liquid  in the tank, when  it has  been  filled,  is  given  by
                                                    o
                            Eq. 15.5-10 when  t  = pV /w^ (from  Eq. 15.5-3) or r  =  UQAQ/W^  (from  Eq. 15.5-7). Therefore,
                                               0
                            in terms  of the original  variables,
                                                         =  1  -                               (15.5-11)
                                                     -  Г,
                            Thus it can be seen that the final  liquid  temperature is determined entirely  by  the dimension-
                            less  group  UQAQ/IV^CP  which,  for  this  problem,  has  the value  of  2.74.  Knowing  this  we  can
                            find  from  Eq. 15.5-11  that (T  -  TJ/(T S  -  T,) = 0.659, whence  T  = 76°C.
                                                                              o
                                                  o
       EXAMPLE   15.5-2     A  well-insulated  agitated  tank  is  shown  in  Fig.  15.5-3.  Liquid  enters  at  a  temperature  7^(0,
                            which  may  vary  with  time. It is  desired  to control the temperature, T (t), of  the  fluid  leaving
                                                                                   2
      Operation  of  a Simple  the tank. It is  presumed  that the stirring  is  sufficiently  thorough that the temperature in the
      Temperature Controller  tank  is  uniform  and  equal  to the exit  temperature. The volume  of  the liquid  in  the tank, V,
                            and the mass rate of liquid flow, w, are both constant.
                               To  accomplish  the  desired  control, a  metallic  electric  heating  coil  of  surface  area  A  is
                            placed  in the tank, and a temperature-sensing  element is  placed  in the exit  steam  to measure
                            T (t).  These  devices  are  connected  to  a  temperature  controller  that  supplies  energy  to  the
                             2
                            heating coil at a rate Q e  = b(T max  -  T ), in which T  max  is the maximum temperature for  which
                                                         2
                            the controller is designed  to operate, and b is a known parameter. It may be assumed  that the
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