Page 77 - Wire Bonding in Microelectronics
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56     Cha pte r  T h ree



                                   99.99% Gold + beryllium hard, as-drawn
                              21
                                                         ASTM F72
                              20
                    Breaking load
                        (g)   19
                              18
                              17
                               2
                    % Elongation 1
                               0
                                  0    2   6  12   24  50  78  104
                                               Weeks

                                   99.99% Gold + beryllium. Stress-relieved,
                                           1–3% elongation
                              11
                    Breaking load
                        (g)   10
                               9
                               2
                    % Elongation  1
                               0
                                  0    2   6  12   24  50  78  104
                                               Weeks
                                    99.99% Gold + beryllium. Annealed,
                                           4–7% elongation
                               8
                    Breaking load
                               7
                        (g)
                               6
                               7
                    % Elongation  6
                               5
                                  0    2   6  12   24  50  78  104
                                               Weeks


              FIGURE 3-3  The shelf-life aging of bonding wire for 25 µm diameter, gold wire
              with <10 ppm Be, in hard as-drawn, stress relieved, and annealed condition.
              [From ASTM F 72-revised in (2006). Copyright ASTM. Reprinted with
              permission.]



              better neck and looping characteristics, etc.). In contrast, Al wire pri-
              marily still uses the same 1% Si alloy, and thus has changed little,
              improving primarily in uniformity and reproducibility.
                 No equivalent aging studies have been conducted on larger-
              diameter bonding wire, (~100 µm, 4 mil) diameter and larger. How-
              ever, most large-diameter aluminum wires currently used for power
              devices are of 99.99%  Al. These wires are generally used in the
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