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Bonding W ir e Metallur gy and Characteristics   53



                                                            4
                                                            3
                                                4
                                                          2
                    Stress (arbitrary units)  2  A          1  B
                                3








                        1


                         0        5       10        15      0  2
                                     Strain (% elongation)

              FIGURE 3-1  Typical stress (pulling force) versus strain (elongation) curves for
              aluminum bonding wire in two states of hardness: wire (A) is annealed and is
              typical of large-diameter aluminum bonding wire, but also similar to those of Au
              used in TS bonding; (B) is stress-relieved (partially annealed). Its characteristics
              are similar to those used for small-diameter ultrasonic wedge bonding (either Al
              or Au wire). In order to display both curves on the same chart, the stress axis
              was made arbitrary [the breaking load of (A) was approximately one-half that
              of (B)]. On both curves (1) is the elastic region where the stress is proportional
              to the strain, (2) is the proportional or elastic limit, (3) is the region of inelastic
              or plastic deformation, and (4) is the breaking load of the wire. The elongation
              at the breaking point is 15% for (A) and 1.5% for (B).



              If the wire is nondestructively pulled (NDPT), the force must not
              exceed the elastic limit (point 2 in both curves). This produces irre-
              versible metallurgical changes in the wire, which by definition can-
              not be nondestructive (see Sec. 4.3).


         3.3  The Shelf-Life Aging of Bonding Wires
              High-volume manufacturers receive their wire on “just-in-time”
              delivery, and use wire within a week or month of receiving shipment,
              and they are not concerned about aging properties. However, small
              organizations and those that only occasionally use a particular type/
              size of wire need to be concerned about the long-term storage (aging)
              properties of many types of bonding wire. Some discard wire after an
              arbitrary period, such as 3 or 6 months. They are not willing to risk a
              change in its metallurgical properties which could affect yield from
              an existing bonding machine setup. In the mid-1980s, ASTM (Com-
              mittee F 1.07) had several wire manufacturers systematically study
              the actual aging properties of both Au and Al, 25 µm (1 mil) diameter
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