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416                              Advances in Eco-Fuels for a Sustainable Environment




                                           Oil


                                   Alcohol     Catalyst






                                      Phase seperation




                              Crude glycerin   Crude biodiesel
                           (glycerol/alcohol/catalyst)


                                                   Refining
                              Glycerin
                             wastewater

                             Prerefining                  Biodiesel


                                       Alcohol + Catalyst
                   Glycerin
                 (80% glycerol)
         Fig. 15.7 Transesterification process employed to obtain biodiesel.

          Table 15.2 Viscosity, density, cetane number, and flash point measurements of six oil methyl
          esters

                                     2               3
                           Viscosity mm /s  Density kg/m  Cetane     Flash
          Methyl ester     (at 313K)       (at 288K)      number     point (K)
          Soybean oil      4.29            855            51.8       432
          Corn vegetable oil  4.5          880            52.5       439
          Palm oil         5.7             880            62         431
          Sunflower oil    4.16            880            49         439
          Fish oil         4.45            881            52.4       428
          Chicken fats     4.35            876            54.8       440


         The BTE is determined by the calorific value of the biodiesel, and higher calorific
         value betters the BTE. The calorific value of biodiesel is fairly high and varies among
         different biodiesels. But compared to diesel, the fuel calorific value of biodiesel is less.
         Hence, the BTE of biodiesel is lower than that of diesel. The BTE characteristics can
         also be affected based on the oxygen content present in the biodiesel, and the more
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