Page 80 - An Introduction to Microelectromechanical Systems Engineering
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Advanced Process Tools                                                         59

                            Table 3.4  Example Solutions for Electroplating Selected Metals
                            Metal      Solution
                            Gold       KAu(CN) :K C H O :HK PO :H O
                                                   6
                                                 3
                                               2
                                                             4
                                                       7
                                                          2
                                                                2
                                                     5
                                       NaAuSO :H O
                                              3
                                                 2
                            Copper     CuSO :H SO :H O
                                            4
                                                    2
                                              2
                                                 4
                            Nickel     NiSO :NiCl :H BO :H O
                                                   3
                                                2
                                            4
                                                      3
                                                        2
                            Permalloy  NiSO :NiCl :FeSO :H BO :C H NNaSO :H SO :H O
                                                             7
                                                               4
                                                     4
                                                        3
                                                2
                                                           3
                                            4
                                                                        2
                                                                      3
                                                                           4
                                                                             2
                            Platinum   H PtCl :Pb(CH COOH) :H O
                                                   2
                                                         2
                                         2
                                                            2
                                             6
                            Aluminum   LiAlH :AlCl in diethyl ether
                                                 3
                                            4
                      Electroplated MEMS structures can take the shape of the underlying substrate
                  and a photoresist mold. First, a conducting seed layer (e.g., of gold or nickel) is
                  deposited on the substrate. In the simplest approach, thick (5- to 100-µm) resist is
                  then deposited and patterned using optical lithography (see Figure 3.19). The larg-
                  est aspect ratio achievable with optical lithography is approximately three, limited
                  by resolution and depth of focus. In LIGA, optical lithography is replaced with
                  x-ray lithography to define very high aspect ratio features (>100) in very thick (up
                  to 1,000 µm) poly(methylmethacrylate) (PMMA), the material on which Plexiglas ®
                  is based. The desired metal is then plated. Finally, the resist and possibly the seed
                  layer outside the plated areas are stripped off.
                                  UV or x-rays
                                               Mask
                        Resist
                              1. Resist exposure               2. Resist development
                                                Metal






                                               Plating
                                               base
                               3. Electroplating                4. Removal of resist
                  Figure 3.19  Illustration of mold formation using either optical or x-ray lithography and electro-
                  plating (LIGA).
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