Page 78 - Basic Gas Chromatography
P. 78

P2250
               —_
               3
                 joo
                    SPB-35
                            SPB-20
                          3
                             500F-SPB-1
                                 400+
                  800}-
                         600/-
                     700}
    Phases  Stationary   of  Classification   GLC   for  Phases   65      whose   determined.   |   900   Caap  “pis  1  F  VZ)  sanen  spjousayoy  300;   arrange-  ‘ses   te   Jot   Tg  tt       gg   200   the   of   10   5   35   30   25   20   615   50   45+   40   down   (%)  content  Phenyl   one   Any   4.4.   Fig.   of  number   of   Effect  stationary   on  groups  phenyl  tricresyl-  measured   as  polarity  phase   by   Reprinted  values.

               between
                    procedure
                  measure
                           should
                         ten
                                  station-
                             and
                         that
    Stationary   phase   are   interaction   provide   a   this   reasoned   five   probes   ten  of  Rohrschneider—   for   13   The   average   goes   one   short.   example,   indicating   OV-202   polymers   Common   Temp.   Lower   20   20   100   20   50   20   20   0   0   20   60   20   20
           Stationary   values   they   about   He   original   the   that   values   polarity?   of   the   as   falls   For   hydrogen   Consider   these   two   Some   Pyrid   0   25   42   43   126   202   299   305   310   386   510   791
           the   A/   intermolecular   details   [7].   further.   of   out   compilations   the   AJ   specifying   value   increases   system   n-butanol,   forming   System?   that   Limits   for   0   849
           on   five   together   More   Rose   some   turned   gives   polarity   the   interaction.   for   by   N-Pr   12   65   67   154   243   374   463   468   492   $72   833   1106
          and   a set   of   of   and   and   step   that   has   Most   4.4   in   use   increasing   the   where   value   indicating   Temperature   Probes*   Ket   0   3   44   45   117   162   250   355   358   338   368   581   763
          squalane   and   extent   phase,   phase.   Supina   one  went   and   five   It   many.   Table   of  any   to   that   is   strong   high   probably   McReynolds   values   and      Alc   0   10   55   57   83   158   321   233   238   369   536   733   872
          on   the   stationary   by   [8]   than   homologs.   too   5.   only   according   shows   That   particularly   alcohols,   the   Constants   0
          run   determined,   stationary   paper   are   list   numbers   much?   unusually   for   identical   Benz   21   16   17   41   119   176   144   146   228   322   492   629
          are   be   measure   the   of   the   the   McReynolds   better   be   higher   values   values   is   4.4   clearly   how   an   with   uses   have   McReynolds   Trademark
          probes   is   to   to   and   polarity   found   in   would   by   index   McReynolds   Table   and   But   indicate a   has   strongly   there   any   They   Phases   Phase   OV-210®   20M®   Benzene   n-Butanol   2-Pentanone   Nitropropane   Pyridine


          five   polarity   serves   probe   the   be   1970   replaced   ten   McReynolds   phases.   Are   in   numbers   table.   can   phosphate   Are   4.4   87¢   300®   Tricresylphosphate   and   Benz   =   =   =   =   =   Registered

   64     All   Each   the   of   can   In   probes   be   hence   ary   ment   five   the   value   interacts   OV-210.   TABLE   Stationary   Stationary   Squalane   Apolane   OV-1®   OV-101®   Dexsil   OV-17®   QOF-1   OV-202®   OV-225®   Carbowax   DEGS   OV-275®   *   Alc   Ket   N-Pr   Pyrid   =   ®
   73   74   75   76   77   78   79   80   81   82   83