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65                                         by   the   Concepts   of   have   early   from    Most   be   inter-   not   not
                                                measured   from   courtesy   the   supplies   to verify   percent-   polymers   is   method,   stationary   empirical   would   have   will   of Hartkopf   consulted.

               —_                                 PA,          (which   The McReynolds
                 P2250                   gg   45+   as  polarity   Bellefonte,   Chromatography:   Reproduced   important   exhausted   used   increasing   silicone   which   the   for   good   a   the   approaches.   forces   efforts   phases   works   be   can
               3                          50                     in                                   dipolar   and


                 joo   SPB-35            Tg   35   40   (%)   phase   Inc.,   M.,   J.   140.   p.   viscosity   and   was   replace   QF-1.   has   been   containing   five   for   SP-2250,   for   some   utility   selecting   extend   or  refine   theoretical   intermolecular   forces,  dispersion   These   stationary   the   [13]   Carr



     GLC                                 tt   30   25   content   stationary   Supelco   of   Miller,   1987,  York,   length   comparison   to  made   replaced   values   plot   a   (except   show   means   for   to   of   of   bonding.   information,   and

     for                  3   SPB-20      20   Phenyl   on  groups   permission   From   New   chain   of   were   OV-210   equivalency.   McReynolds   polymers   shows   columns   attempted   variety   types   phases:   hydrogen   selecting   [12],
     Phases                             te   615   phenyl   with   May   1985.   Inc.,   in   type   polymers   their   five   silicone   4.4   examples   simple   a   have   using   a   four   stationary   of   process   of   further   For   Risby   [11],


     Stationary                        ‘ses   Jot   10   5   of  number   Reprinted   3,   No.   IV,   &  Wiley   Sons,   differences   This   new   example   for   proof   of   these   of   groups.  Figure   WCOT   silica   These   still  lacking   separation.   of  workers   by   or  three   types   two   the   here.   Snyder



     of       |   900   800}-   700}   600/-   500F-SPB-1   400+   300;       200   of   values.   Vol.   John   Sons,   Inc.   for  except   polarity).   on   when   polymers;   of   sum   polarity   in   fused   data).   are   we   given   McReynolds   that   characterize   one   or   on  impact   further   [10],
     Classification   Caap  “pis  1  F  VZ)  sanen  spjousayoy   4.4.   Fig.  Effect   McReynolds   Reporter,  Supelco   and  Contrasts,   &  Wiley  John   identical   affect   little   GC   of   days   of   old   provided  values   Also,   the   the  increase   phenyl   of   ages   bonded   on   packed  column   clearly   but   a   for  phase   Studies  Other   Various  groups   of   data   assumed   have   sufficient   to   and  actions,   much














    Phases   whose   determined.   between   measure   procedure   ten   that   should   and   station-   arrange-   the   of   down   one   Any   tricresyl-   it   that   bonds.   and   are   Limits   Upper   125   260   375   375   450   375   125   250   275   300   225   200   275

    Stationary   phase   are   interaction   provide   a   this   reasoned   five   probes   ten  of  Rohrschneider—   for   13   The   average   goes   one   short.   example,   indicating   OV-202   polymers   Common   Temp.   Lower   20   20   100   20   50   20   20   0   0   20   60   20   20

           Stationary   values   they   about   He   original   the   that   values   polarity?   of   the   as   falls   For   hydrogen   Consider   these   two   Some   Pyrid   0   25   42   43   126   202   299   305   310   386   510   791




           the   A/   intermolecular   details   [7].   further.   of   out   compilations   the   AJ   specifying   value   increases   system   n-butanol,   forming   System?   that   Limits   for   849
           on   five   together   More   Rose   some   turned   gives   polarity   the   interaction.   for   by   N-Pr   0   12   65   67   154   243   374   463   468   492   $72   833   1106
          and   a set   of   of   and   and   step   that   has   Most   4.4   in   use   increasing   the   where   value   indicating   Temperature   Probes*   Ket   0   3   44   45   117   162   250   355   358   338   368   581   763
          squalane   and   extent   phase,   phase.   Supina   one   went   and   five   It   many.   Table   of  any   to   that   is   strong   high   probably   McReynolds   values   and      Alc   0   10   55   57   83   158   321   233   238   369   536   733   872



          on   the   stationary   by   [8]   than   homologs.   too   5.   only   according   shows   That   particularly   alcohols,   the   Constants   0
          run   determined,   stationary   paper   better   are   list   numbers   much?   unusually   for   identical   Benz   21   16   17   41   119   176   144   146   228   322   492   629
          are   be   measure   the   of   the   the   McReynolds   be   higher   values   values   is   4.4   clearly   how   an   with   uses   have   McReynolds   Trademark
          probes   is   to   to  serves   and   polarity   found   in   would   by   index   McReynolds   Table   and   But   indicate a   has   strongly   there   any   They   Phases   Phase   OV-210®   20M®   Benzene   n-Butanol   2-Pentanone   Nitropropane   Pyridine   Registered


          five   polarity   probe   the   be   1970   replaced   ten   McReynolds   phases.   Are   in   numbers   table.   can   phosphate   4.4   87¢   300®   Tricresylphosphate   and   Benz   =   =   =   =   =

   64     All   Each   the   of   can   In   probes   be   hence   ary   ment   five   the   value   interacts   Are   OV-210.   TABLE   Stationary   Stationary   Squalane   Apolane   OV-1®   OV-101®   Dexsil   OV-17®   QOF-1   OV-202®   OV-225®   Carbowax   DEGS   OV-275®   *   Alc   Ket   N-Pr   Pyrid   =   ®
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