Page 489 - Cascade_Biocatalysis_Integrating_Stereoselective_and_Environmentally_Friendly_Reactions

Index 465
thiamine diphosphate (ThDP)-dependent umbelliferone 320
enzyme 315 unspecific peroxygenases (UPOs) 3, 15, 16
thioesterification 184 β-ureidopropionase. See N-carbamoyl-β-alanine
thioesters 180 amidohydrolase (NCβAA)
– dynamic kinetic resolution of 188–193
D-threose 352, 355 v
toluene oxidation 52 vanillin 53, 414
Trametes versicolor laccase (TvL) 11 verapamil metabolism 102
transaminases 300 veratryl alcohol (VA) 3, 11
ω-transaminases (TAs) 65–83, 207 versatile peroxidases (VPs) 5, 11–13
– cascade reactions 80–82 vitamin D 3 metabolism 107
– catalyzed amination 77
– catalyzed reactions 68, 69 w
– linear cascade reactions involving 69–72 Wacker oxidation 448, 449
α-transaminases 66 whole-cell biocatalysts 114–115, 235, 250,
transamination 203 252, 253, 260
transglycosylation 136, 142, 151 wild-type FucA 343
transition-metal-catalyzed heterogeneous wild-type transketolase 330–331
hydrogenation 59 Wittig reaction 443, 444
transketolase (TK) 207
– activity by in vivo selection 329–330 x
– activity in E. coli 331–334 xenotransplantation antigen glycan synthesis
– activity in vitro 317–329 148–149
– applications of 315–335 xylene-monooxygenase (XMO) 52
– microbial 315 xylulokinase (XK) 318
triose phosphate isomerase (TPI) 317 D-xylulose 5-phosphate (D-X5P) 317, 318

u
UDP-Gal and UDP-GalNAc synthesis 142
ultra low molecular weight (ULMW) heparin
145