Page 130 - Biodegradable Polyesters
P. 130

108  4 Synthesis, Properties, and Mathematical Modeling of Biodegradable Aliphatic Polyesters

                    42. Park, S.S., Jun, H.W., and Im, S.S. (1998)  poly(ethylene terephthalate). Ind. Eng.
                       Kinetics of forming poly(butylene suc-  Chem. Res., 31, 769–777.
                       cinate) oligomer in the presence of  52. Ravindranath, K. and Mashelkar, R.A.
                       MBTO catalyst. Polym. Eng. Sci., 38,  (1986) Poly(ethylene terephthalate)-II.
                       905–913.                         Engineering analysis. Chem. Eng. Sci., 41,
                    43. Bikiaris, D.N. and Achilias, D.S. (2006)  2969–2987.
                       Synthesis of poly(alkylene succinate)  53. Choi, K.Y. (1987) A modeling of
                       biodegradable polyesters. Mathematical  semibatch reactors for melt transes-
                       modelling of the esterification reaction.  terification of dimethyl terephthalate
                       Polymer, 47, 4851–4860.          with ethylene glycol. Polym. Eng. Sci., 27,
                    44. Achilias, D.S. and Bikiaris, D.N. (2006) in  1703–1712.
                       Environmental Toxicology, WIT Transac-  54. Ravindranath, K. and Mashelkar, R.A.
                       tions on Biomedicine and Health, vol. 10  (1986) Polyethylene terephthalate-I.
                       (eds A.G. Kungolos, C.A. Brebbia, C.P.  Chemistry, thermodynamics and trans-
                       Samaras, and V. Popov), Wessex Institute  port properties. Chem. Eng. Sci., 41,
                       of Technology, pp. 309–318.      2197–2214.
                    45. Bikiaris, D.N. and Achilias, D.S. (2008)  55. Ravindranath, K. and Mashelkar, R.A.
                       Synthesis of poly(alkylene succinate)  (1984) Finishing stages of PET synthesis:
                       biodegradable polyesters, Part II:  a comprehensive model. AIChE J., 30,
                       mathematical modelling of the poly-  415–422.
                       condensation reaction. Polymer, 49,  56. Ravindranath, K. and Mashelkar, R.A.
                       3677–3685.                       (1981) Modeling of poly(ethylene tereph-
                    46. Hu, L., Wu, L., Song, F., and Li, B.G.  thalate) reactors. I. A semibatch ester
                       (2010) Kinetics and modeling of melt  interchange reactor. J. Appl. Polym. Sci.,
                       polycondensation for synthesis of  26, 3179–3204.
                       poly(butylene succinate-co-butylene  57. Ma, Y., Agarwal, U.S., Sikkema, D.J., and
                       terephthalate), 1. Esterification. Macro-  Lemstra, P.J. (2003) Solid-state polymer-
                       mol. React. Eng., 4, 621–632.    izationofPET:influenceofnitrogen
                    47. Kostoglou, M. and Bikiaris, D.N. (2011)  sweep and high vacuum. Polymer, 44,
                       Kinetic analysis of nanocomposites pre-  4085–4096.
                       pared in situ consisting of an aliphatic  58. Parashar, M.K., Gupta, R.P., Jain, A.,
                       biodegradable polyester and fumed silica  and Agarwal, U.S. (1998) Reaction
                       nanoparticles. Macromol. React. Eng., 5,  rate enhancement during swollen-
                       178–189.                         state polymerization of poly(ethylene
                    48. Yamada, T. (1996) Effect of reaction  terephthalate). J. Appl. Polym. Sci., 67,
                       variables on TPA-EG continuous esterifi-  1589–1998.
                       cation with recycling in PET production  59. Ma, Y. and Agarwal, U.S. (2005) Solvent
                       process. Polym. React. Eng., 4 (1), 1–45.  assisted post-polymerization of PET.
                    49. Rieckmann, T. and Volker, S. (2001)  Polymer, 46, 5447–5455.
                       Micro-kinetics and mass transfer in  60. Bikiaris, D.N., Achilias, D.S., Giliopoulos,
                       poly(ethylene terephthalate) synthesis.  D., and Karayannidis, G.P. (2006) Effect
                       Chem. Eng. Sci., 56, 945–953.    of activated carbon black nanoparti-
                    50. Otton, J. and Ratton, S.J. (1998) Investi-  cles on solid state polymerization of
                       gation of the formation of poly(ethylene  poly(ethylene terephthalate). Eur. Polym.
                       terephthalate) with model molecules:  J., 42, 3190–3201.
                       kinetics and mechanism of the catalytic  61. Achilias, D.S. (2007) A review of
                       esterification and alcoholysis reactions.  modeling of diffusion controlled poly-
                       I. Carboxylic acid catalysis (monofunc-  merization reactions. Macromol. Theory
                       tional reactants). Polym. Sci. Polym.  Simul., 16, 319–347.
                       Chem. Ed., 26, 2183–2197.     62. Duh, B. (2002) Semiempirical rate
                    51. Lei, G.D. and Choi, K.Y. (1992) Kinetics  equation for solid state polymeriza-
                       of melt transesterification of dimethyl  tion of poly(ethylene terephthalate). J.
                       terephthalate with bis(2-hydroxyethyl)  Appl. Polym. Sci., 84, 857–870.
                       terephthalate in the synthesis of
   125   126   127   128   129   130   131   132   133   134   135