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Biodiesel and Ethanol in Engines     277

               results in higher smoke because there is a lesser amount of oxygen
               available. Hence, overloading the engine will result in a very black
               smoke. It is observed that smoke level decreases with ethanol fumi-
               gation. Fumigation of ethanol starts precombustion reactions before
               and during a compression stroke, resulting in reduced chemical delay
               because the intermediate products such as peroxides and aldehydes
               react more rapidly with oxygen than with original hydrocarbons.
               This shortening of the delay period curbs thermal cracking, which is
               responsible for soot formation that results in a reduction of smoke. It
               is observed that at an engine speed 800 rpm and at no load, the smoke
               level is decreased by 91.66, 75, and 41.59 percent at ethanol fumiga-
               tion rates of 1.06, 1.45, and 2.06 kg/h (45.00, 54.57, and 62.17 percent
               diesel substitution), respectively, when compared to the smoke level
               under diesel fuel operation. At a high load of 6.31 kW, the smoke
               level is decreased by 68.18, 50.10, and 40.90 percent at ethanol fumi-
               gation rates of 1.06, 1.45, and 2.06 kg/h, respectively, when compared
               to the smoke level under diesel fuel operation.

               8.2.8  Effect of Brake Power on Exhaust Gas Temperatures
                       at Various Ethanol Fumigation Rates
               We can see in Fig. 8.14 that exhaust gas temperature increases with an
               increase in brake power at constant speed. The temperature inside
               the combustion chamber increases while brake power is increased,



                   180        Fumigation rate
                             0.00 kg/h (0.00%)
                             1.06 kg/h (45.00%)
                  Exhaust gas temperature (°C)  140
                   160
                             1.45 kg/h (54.57%)
                             2.06 kg/h (62.17%)



                   120


                   100


                    80

                          0      1     2     3      4     5     6      7
                                         Brake power (kW)
               FIGURE 8.14  Effect of fumigation on exhaust gas temperatures at various
               brake powers at a speed of 800 rpm.
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