Page 187 - Carbon Nanotube Fibres and Yarns
P. 187

Carbon nanotube yarn structures and properties   177


                 Now, if future commercial CNT yarns can utilize their theoretical
              strength to the same level as the commodity textile fibers, they can be ex-
              pected to achieve a specific strength in the range of 1.5–2.5 N/tex, which
              have already been reported by a number of research groups. If the utilization
              ratio can be increased to that of the high-performance fibers, future CNT
              yarns may be expected to reach specific strength between 4.3 and 7 N/tex
              and specific modulus between 161 and 325 N/tex. These values translate into
                                                                             3
              7.7–12.6 and 290–585 GPa, respectively, based on a density of 1.8 g/cm .
              These strength and modulus are higher than the mechanical performance
              achieved by any commercially manufactured fibers.


              7.7  Summary and future prospect

              CNTs possess very high mechanical properties combined with excellent
              electrical and thermal conductivity. Fiber and yarn are the most efficient
              structures known to researchers for utilization of these properties. The CNT
              fibers and yarns of today have utilized only a small fraction of the mechan-
              ical, electrical, and thermal properties of the constituent CNTs. The struc-
              tural mechanics of conventional textile yarns is well understood and in many
              cases provides useful clues for understanding the relationship between the
              structure and properties of CNT yarns. The strong van der Waals force, the
              geometrical disorder of as-synthesized CNTs and the unique nanotube in-
              terfacial properties present challenges as well as opportunities for the research
              and development of higher performance CNT fibers and yarns. Maximizing
              densification and alignment of the CNTs are two widely used tools to im-
              prove the load transfer efficiency and conductivity between nanotubes in
              CNT fibers and yarns. Lessons from textile industry tell us that CNT fiber
              has a good prospect to become the strongest fiber we have ever had.


              References

                [1]  M.-F.  Yu, O.  Lourie, M.J.  Dyer, K.  Moloni, T.F.  Kelly, R.S.  Ruoff, Strength and
                  breaking mechanism of multiwalled carbon nanotubes under tensile load, Science
                  287 (5453) (2000) 637–640.
                [2]  R. Zhang, Q. Wen, W. Qian, D. Su, Q. Zhang, F. Wei, Superstrong ultralong carbon
                  nanotubes for mechanical energy storage, Adv. Mater. 23 (2011) 3387–3391.
                [3]  J. Hone, M.C. Llaguno, N.M. Nemes, A.T. Johnson, J.E. Fischer, D.A. Walters, et al.,
                  Electrical and thermal transport properties of magnetically aligned single wall carbon
                  nanotube films, Appl. Phys. Lett. 77 (5) (2000) 666–668.
                [4]  M. Miao, Yarn spun from carbon nanotube forests: production, structure, properties
                  and applications, Particuology 11 (4) (2013) 378–393.
   182   183   184   185   186   187   188   189   190   191   192