Page 63 - Chalcogenide Glasses for Infrared Optics
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Chalcogenide Glasses      41



                         500






                         400


                       Softening point (°C)  300











                         200
                            As S 3
                              2




                         100
                                 100           200          300
                                       Knoop hardness
              FIGURE 2.13  Correlation of softening point and Knoop hardness for
              chalcogenide glasses.



              four elements. Even with a softening point of 500°C, Knoop hardness
              was less than 250.


              2.5.2  Thermal Coefficients of Expansion
              The higher the softening point, the smaller the thermal expansion
              coefficient. Results obtained from 30 samples are plotted in Fig. 2.14.
              The correlation is very general in part because the glasses measured
              are from different systems some with four elements. Many factors
              may affect results.


              2.5.3 Density
              The densities of selenium and tellurium glasses containing silicon,
              germanium, arsenic, and phosphorus are almost a linear function of
              the calculated average molecular weight of the glass composition.
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