Page 581 - Corrosion Engineering Principles and Practice
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544    C h a p t e r   1 3                                                                                                        C a t h o d i c   P r o t e c t i o n    545



                 13.4  How Cathodic Protection Works in Concrete
                      The main causes of corrosion of steel in concrete are chloride attack
                      and carbonation. These two mechanisms are unusual in that they do
                      not attack the integrity of the concrete. Instead, aggressive chemical
                      species pass through the pores in the concrete and attack the steel.
                      This is unlike normal deterioration processes due to chemical attack
                      on concrete.
                         Most problems associated with corrosion of steel in concrete are
                      not due to the direct loss of steel but to the growth of the corrosion
                      oxide products which eventually can lead to cracking and spalling of
                      the  concrete  cover  (Fig.  13.19).  Structural  collapses  of  reinforced
                      concrete  structures  due  to  corrosion  are  rare.  The  most  common
                      problem caused by corrosion is spalling of concrete cover, which has
                      caused  a  few  deaths  and  accidents  in  recent  history.  It  has  been
                      suggested that less than 100 µm of steel-section loss is needed to start
                      cracking and spalling of the concrete. The actual amount needed will
                      depend on the geometry in terms of cover, proximity to corners, rebar
                      spacing, bar diameter, and the rate of corrosion [10].
                         A number of fundamental measures can be taken to address the
                      problem  of  reinforcing  steel  corrosion.  However,  an  important



































                      FIGURE 13.19  Corrosion ravaged columns of a highway bridge in Illinois.
                      (Courtesy of Vector Corrosion Technologies)
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