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CHAPTER 19 • Future Climatic Change  347


           Even after human CO emissions begin to fall, the  amount than CO . Most of the land that can be used to
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        slowly decreasing yearly CO emissions continue to   grow rice is already in irrigation, and future increases in
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        push the atmospheric concentration to even higher lev-  the extent of these CH -emitting “rice wetlands” are
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        els. Not until about a century after the peak in CO  likely to be negligible. As the number of humans on
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        emissions does the rate of additional input by humans  Earth levels out after mid-century (Figure 19–1), the
        drop below the rate of removal by the ocean. At this  number of CH -emitting livestock that people tend
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        point, the CO concentration begins to decline.      should also stabilize.
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           Over even longer intervals, other considerations    Unlike CO , methane stays in the atmosphere for
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        come into play. Over the course of hundreds to thou-  only a decade before being oxidized to other gases. One
        sands of years, the acidity produced by the CO      interesting question is whether a warmer future world
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        absorbed in the deep ocean dissolves some of the CaCO  will cause large Arctic reservoirs of now-frozen methane
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        on the seafloor (Figure 19–4B). This process neutralizes  to melt. If that happens, unknown amounts of CH gas
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        CO in the ocean. The ultimate fate of our excess CO  could be added to the greenhouse effect as a positive
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        pulse will be a slow-acting chemistry experiment in the  feedback (Box 19–1).
        deep ocean.                                            Future additions of SO and carbon aerosols to the
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                                                            atmosphere by humans are also difficult to predict. The
                                                            positive impact of environmental cleanup efforts in some
        19-3 Other Human Effects on the Atmosphere
                                                            industrialized nations will be countered to an unknown
        Other emissions by humans may also be important.    extent by increased burning of sulfur-rich coal in nations
        Methane production is likely to increase, but by a smaller  still undergoing industrialization. A net increase in SO
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                             BOX 19-1    CLIMATE INTERACTIONS AND FEEDBACKS
                                        Will Frozen Methane Melt?

              ethane exists as a gas in the atmosphere, but in
                                                                Increase in
          MEarth’s colder regions it also occurs in a frozen form  greenhouse gases
          known as methane clathrate, a mixture of methane and                    Global
                                                                                  warming
          slushy ice. Clathrates occur in deep-ocean sediments
          along continental margins, where the pressure pro-                     Increased
                                                                                 warming
          duced by overlying water and sediments makes CH stable
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          at temperatures well above freezing (5°C or more).
          Clathrates also occur in the Arctic, both in shallow ocean
          sediments and below permafrost on land. The volume of
          CH stored in these reservoirs is enormous, far exceed-                                 Melting
            4                                                                                    of frozen
          ing the volume in all wetlands and livestock reservoirs
                                                                                                   CH 4
          combined.
             Without major changes in climate, most methane
          clathrate will remain trapped in its present form, but         Increase in
          with the large future warming projected for north polar         CH 4  gas
          regions, the question is whether or not it will remain
          trapped in the slushy ice. Permafrost is expected to con-
                                                            Methane clathrate feedback Future warming of the deep
          tinue to melt from the top down, but will this warming
                                                            coastal ocean and melting of polar permafrost could release
          reach deep enough to tap the methane clathrates and  frozen methane cause additional global warming.
          liberate some of the trapped CH to the atmosphere?
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             Because it will take centuries for the higher surface  warming of the poles or the deeper ocean causes the
          temperatures to penetrate far into permafrost and ocean  release of even a small fraction of the vast mass of frozen
          sediments, most (but not all) scientists doubt that large  methane, it could provide a significant positive feedback
          amounts of CH will be released. Still, if future greenhouse  to the initial greenhouse-gas warming.
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