Page 209 - Fiber Fracture
P. 209

194                                                            H.U. Kiinzi

                Table I. Texture and Young’s modulus E  of drawn  and restored (4 months at 2OOC) 38  pm diameter Cu
                wires
                                               As drawn      After 4 months at 20°C
                Fraction of (100) texture (%)   66           88
                Fraction of (1 11) texture (%)   34          12
                E measured (GPa)               96            12
                E  Voigt average (GPa)         I09           82
                E Reus average (GPa)            86           12
                E average of Voigt + Reuss (GPa)   91        I1



                  Small values for Young’s modulus may be beneficial in very thin wires to improve
                the resistance to fracture failure. Machines used to handle thin wires are always much
                stronger (smaller compliance) than the wires. The small elastic forces produced by the
                wire in case of a temporary feeding problem will not stop the machine. The machine
                therefore imposes a given elongation, and the  smaller Young’s  modulus,  the smaller
                the corresponding stress. Well-pronounced textures also have an influence on the yield
                stress through the Schmid factor. For fcc metals and traction along the (1 1 1) direction
                or along the axis of  wire with a (1 11) texture the yield stress is 3.67 times the critical
                shear stress. The same is true for a (1 10) texture. For a traction near the (100) direction
                this value falls to its minimum that is near 2.4. Textural strengthening may therefore
                contribute up to 50% with respect to the (100) direction and about 20% with respect to a
                polycrystalline wire (Grewen, 1970).
                  Experimental observations made by Rieger (1974) confirm the superior strength of
                (1 11) fiber textures. He measured the mechanical properties of Cu  and Cu-Zn  alloys
                with variable proportions of (1 1 1) and (100) fiber textures and observed that the tensile
                strength increases by  more than 3 times when a (100) tcxture is replaced by  a (1 11)
                texture.  Kuo  and Starke (1985)  made  a  similar study on  A1  alloys but  found much
                smaller differences.
                  Unfortunately, the  directional dependence is  similar to  that of  Young’s  modulus.
                The stress-reducing effect of Young’s modulus in textured wires is therefore partially
                compensated by  the corresponding reduction of the yield stress. But the reduction of
                Young’s modulus between its extremal values in the (1 1 1) and (100) directions is about
                twice the reduction of the yield stress between the same directions.
                Melt-Spinning Defects

                  Compared to drawing which is a well established and slow process, melt spinning
                for metals is more recent, much easier and faster. Clearly, melt-spun products do not
                have the regular round  shape and the  surface quality of  drawn wires. But for many
                applications, such as fiber reinforcement, this is not the primary concern. A parameter of
                much greater importance in this field is the mechanical strength. In fact, melt spinning
                is  particularly useful  for  the  production of  continuous- or  fixed-length  filaments of
                amorphous metals. Many  alloys  can  be  spun  to  fibers,  ribbons  and  foils  that  have
                thickness dimensions of only a few tenths of a micrometer and widths from about 100
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