Page 267 - Geochemical Remote Sensing of The Sub-Surface
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240                                       1-1. Yang, F.D.  Van der Meer and J. Zhang

           carbonate  in  soil.  Four  channels,  at  the  wavelength  ranges  of  1.550-1.650  ~tm, 1.985-
           2.085  ~tm, 2.037-2.137  ~tm and 2.039-2.193  ~tm, were used for anomaly extraction.  The
           anomaly overlies a subsurface heavy-oil reservoir (Zhu and Wang,  1991).



           Vegetation  stress

              Hydrocarbon  microseepage  creates  a  reducing  environment  in  the  soil  and
           overburden at depths  shallower than would be expected in the  absence of microseepage.
           The presence  of hydrocarbons  stimulates  the  activity of hydrocarbon-oxidising  bacteria,
           which  decreases  oxygen  content  of  the  soil  whilst  increasing  its  contents  of  carbon
           dioxide  and  organic  acids.  These  changes  affect pH  and Eh of soil,  which  in turn  affect
           the solubilities  of  elements that are plant nutrients  and consequently their availability to
           vegetation  (Schumacher,  1996).  This  may  affect  the  root  structure  of  vegetation  and
           ultimately influence its vigour and hence its spectral reflectance (Feder,  1985).
               Remote  sensing  of anomalous  (or  stressed)  vegetation  takes  two  forms.  One  is the
           mapping  of  the  distribution  of  different  species  of  vegetation  and  the  differences  in
           vigour  and  morphology  within  each  species  (Brooks,  1972;  Siegel,  1974).  Vegetation
           that  is typically prolific  is often  stunted or absent  in areas  of unusual  soil  environments.
           On  the  other  hand,  some  species  thrive  in  environments  that  are  toxic  to  most  other
           species  and  are  recognised  as  geobotanical  indicators.  The  second  approach  is  to
           determine differences  in spectral characteristics between healthy and stressed vegetation.
           The  spectral  signatures  of  vegetation  associated  with  hydrocarbon  microseepage  have
           been  extensively studied.  The main targets of attention  are the  green peak (at 0.56  ~tm),
           the  red  trough  (at  0.67  ~tm), the  shift  of  position  of  red  edge  and  the  height  of  the
           infrared shoulder.
              In  both  cases,  normal  or  background  variability  in  the  distribution  and  vigour  of
           various  species  presents  complications  that need  to be  taken  into  account.  Factors  such
           as  bedrock  geology,  soil  type,  slope,  soil  moisture  and  climate  can  have  a  more
           pronounced  effect than that due  to the presence  of hydrocarbons  (Rock,  1984;  Klusman
           et  al.,  1992).  Nevertheless,  numerous  accounts  have  been  published  of the  detection  of
           hydrocarbon-induced vegetation anomalies by remote sensing.
              McCoy and Wullstein (1988) analysed leaves of sagebrush and greasewood  from the
           Blackburn  oil  field  in  Nevada  and  reported  a  halo  anomaly  of  high  Mn:Fe  ratios
           surrounding the productive part of the field.  McCoy et al. (1989) revisited the Blackburn
           field and  determined that the  spectral  reflectance  of sagebrush  from the  anomalous  area
           was  lower  than  that  of  sagebrush  from  background  areas.  Bammel  and  Birnie  (1993)
           evaluated  reflectance  in  the  visible  and  near  infrared  regions  (0.45  to  1.1  ~tm) of
           sagebrush  in five areas  in the Bighorn Basin  of Wyoming to  determine  its usefulness  in
           hydrocarbon  exploration.  The  most effective  indicator  of hydrocarbon-induced  stress  in
           sagebrush proved to be a consistent blue shift (to shorter wavelengths) of the green peak
           and  red  trough.  This  shift  is  only  detected  in  areas  where  sagebrush  is  prolific  and
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