Page 522 - Handbook of Battery Materials

16.3 SEI Formation on Carbonaceous Electrodes 495

Electrolyte LiClO 4 /EC–DEC LiClO 4 /EC–DEC LiClO 4 /EC–PC LiClO 4 /EC LiPF 6 /EC–DEC LiPF 6 /EC-DEC LiAsF 6 /PC, 12-crown-4 LiAsF 6 /MF–CO 2 LiAsF 6 /MF–CO 2 LiAsF 6 /MF–CO 2 LiAsF 6 /EC–DEC LiAsF 6 /EC–DEC LiAsF 6 /1,3-dioxolane–EC LiAsF 6 /1,3-dioxolane LiAsF 6 /1,3-dioxolane overleaf) (continued

fibers fibers coke black fibers
type Natural graphite Carbon DB40R
Carbon Graphite Graphite Graphite Graphite Graphite Graphite Petroleum Acetylene Graphite Graphite Graphite Graphite Graphite

Material ClO 4 − ClO 4 − ClO 4 − ClO 4 − EC PF 6 − PF 6 − AsF 6 − AsF 6 − CO 2 AsF 6 − CO 2 AsF 6 − CO 2 AsF 6 − AsF 6 − AsF 6 − AsF 6 − AsF 6 −

s −1 ) − 10 9c × 10 9 × 10 9 × 10 9
k e b (l mol −1 <10 6 <10 6 <10 6 <10 6 10 10 – – × 10 9 9 × 10 9 9 7.7 × 10 9 9 7.7 × 10 9 9 7.7 × 10 9 9 × 10 9 9 × 10 9 9 × 10 9 9 × 10 9 9

V SEI . 0.8 0.8 0.8 1.0 0.65 0.7 0.6 1.7 1.3 1.33 1.2 1.2 1.25 1.2 1.5

and V SEI a (V)
k e
Correlation between Menachem, results) Menachem, results) Menachem, results) Menachem, results)

C. and (unpublished and C. (unpublished and C. (unpublished and C. (unpublished
Table 16.2 Reference [77] [76] [78] [79] [80] [80] [81] [81] [82] [82] [65] Bar-Tow, E. Peled, Bar-Tow, E. Peled, Bar-Tow, E. Peled, Bar-Tow, E. Peled,