Page 523 - Handbook of Battery Materials
P. 523

496  16 The Anode/Electrolyte Interface













                                         Electrolyte  LiAsF 6 /EC–PC  LiAsF 6 /EC–DEC  LiN(CF 3 SO 2 ) 2 /PC–EC,  12-crown-4  SO 2 or PC + LiAsF 6 /MF  SO 2  + LiBr/AN




                                                coke
                                         Carbon type  Graphite  Petroleum  Graphite  Graphite  Carbon fiber







                                         Material  AsF 6 −  AsF 6 −  N(CF 3 SO 2 ) 2 −  SO 2  SO 2



                                         s −1 )  10 9  10 9
                                         k e b (l mol −1  9 ×  9 ×  –  10 10d  10 10d




                                         V SEI a (V)  1.2  1.1  0.75  2.7  2.7 a vs LiRE (or Li/Li + ), V peak in dQ/dV curve or inflection point in V vs Q curves. c Assumed to be similar to that of other esters (like dimethyl oxalate) in Table 16.1.






                                    (continued)                    d Assumed to equal that of O 2 .




                                    Table 16.2  Reference  [83]  [83]  [84]  [85]  [86]  b From Table 16.1.
   518   519   520   521   522   523   524   525   526   527   528