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Engineering properties of spider silk                             199

           6.3.2.4  Creep at constant loads

           Measuring the creep of spider silk was carried out using a microtensile tester wherein
           the fiber can be tested in a horizontal position avoiding difficulty created by
           gravitation.
              The creep data, plotting stretch ratio as a function of the logarithm of time, are
           shown in Fig. 6.11. In general, creep rate increases as the load level increases. As
           the load increases the creep response becomes increasingly nonlinear. In order to
           use linear mathematics in data analyses, the elastic response (or elastic stress) T(l)
           was used instead of the conventionally used strain as a function of time to calculate
           the reduced creep function (t).
                                                               e
              J(t)isdefined as the ratio of the elastic response at time t, T ½lðtފ, to the elastic
                                         e
           response at the moment of loading, T ½lðt r ފ, i.e.,
                       e
                     T ½lðtފ
               JðtÞ¼  e                                                    (6.3)
                     T ½lðt r ފ
               Jð0Þ ¼ 1                                                    (6.4)


           6.3.2.5  Low-frequency sinusoidal stretching
           In a typical sinusoidal stretching experiment, the fiber is kept taut by stretching it to a
           predetermined strain. The fiber is vibrated sinusoidally at predetermined amplitude.
           The stress response s e to the harmonic strain input ε 0 could be either harmonic or


                     1.05
                                                       0.5 gm
                     1.04

                    Stretch ratio λ  1.03              0.4 gm



                     1.02

                                                        0.2 gm
                     1.01
                                                        0.1 gm

                     1.00
                           −1     0     1      2      3      4     5
                                            Log time (s)
           Figure 6.11 Creep data of spider silk obtained at various maximum extension (Ko et al., 2004a;
           Ko, 1976).
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