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6.1 Methods and mechanisms of tack enhancement                        77


                                                 leum-derived   C9-hydrocarbons.   The
                                                 copolymer  resins  are  cycloaliphatic  aro-
                                                 matic hydrocarbon resins and maleic anhy-
                                                 dride-modified  hydrocarbon  resins  are
                                                 useful in promoting pigment wetting.
                                                     Hydrogenated hydrocarbon resins are
                                                 produced  using  the  controlled  hydrogena-
                                                 tion of basic or pure monomer aromatic res-
                                                 ins.  They  are  usually  colorless  and  very
                                                 stable to heat, weathering, and oxidation.
                                                     The hydrocarbon resins are frequently
                                                 used as tackifiers in the pressure-sensitive
                                                                              3
                                                 and  hot-melt  adhesives  markets.  The
                                                 amount  of  the  hydrocarbon  resin  used  in
                                                 these formulations sometimes equals to the
            Figure 6.5. The effect of maleation on glass transition
                                                                        3
            temperature and melting point of aliphatic C5 hydrocar-  weight of the base polymer.  In tire indus-
            bon resin. [Data from Kumar, KD; Tsou, AH; Bhow-  try, 5-15 parts of hydrocarbon resin per 100
            mick, AK, Int. J. Adh. Adh., 30, 200-7, 2010.]
                                                 parts  of  elastomer  is  typically  used  to




































            Figure 6.6. Chemical structures of tackifiers. [Adapted, by permission, from Sasaki, M; Fujita, K; Adachi, M;
            Fujii, S; Nakamura, Y; Urahama, Y, Int. J. Adh. Adh., 28, 372-81, 2008.]
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