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58    G a s , C h e m i c a l , a n d F r e e - E l e c t r o n L a s e r s                                                          Chemical Lasers     59


                         When considering the evolution of kinetic processes, one simply
                      uses the velocity U to relate position and time, using dx = Udt. At high
                      velocities, where compressibility of the gas becomes significant, the
                      flow behavior becomes complicated. This regime is usually defined to
                      occur when the Mach number, M = U/c, becomes greater than ~0.3. For
                      the case of a nonreacting flow with neither friction nor heat addition
                      (isentropic),  the  flow  is  characterized  by  its  stagnation  properties,
                      which correspond to flow conditions after the flow is isentropically
                      brought to rest, given by:

                                                         2
                                      T /T =    1 + 0.5 (γ – 1)M
                                       0
                                                         2 γ/(γ−1)
                                      P /P = [1 + 0.5 (γ – 1)M ]           (3.18)
                                       0
                                                         2 1/(γ−1)
                                      ρ  0 /ρ = [1 + 0.5 (γ – 1)M ]
                      where P, T, and ρ are the static properties and P , T , and ρ  are the
                                                                  0
                                                               0
                                                                         0
                      stagnation properties.
                         Gas flows that travel isentropically through a duct with variable
                      cross section A satisfy Eq. (3.19):
                                       dU/U = (dA/A)/(M – 1)               (3.19)
                                                        2
                      This expression illustrates the principle of operation behind the con-
                      verging-diverging nozzle that is widely used in laser applications. In
                      the converging section, the flow accelerates until it reaches the mini-
                      mum area throat location, where the flow reaches M = 1. It then con-
                      tinues to accelerate beyond the throat in the expanding region, where
                      M continues to increase to supersonic values, resulting in much lower
                      pressure, static temperature, and density.
                         In parallel, one also flows the secondary flow of hydrogen that
                      reacts with the fluorine atoms to produce the vibrationally excited HF
                      and  the  associated  heat  of  reaction.  The  addition  of  heat  tends  to
                      drive  the  flow  toward  Mach  1  conditions,  or  the  so-called  thermal
                      choking case. Avoiding this condition is a major concern in chemical
                      laser designs. Thermal choking of supersonic flows leads to a variety
                      of unfavorable behaviors, such as reduced velocity, increased density
                      and  pressure,  higher  temperatures,  large  optical  path  difference
                      (OPD)  effects  associated  with  density  variations,  and  feedback  of
                      flow behavior into upstream flow regions. To avoid thermal choking,
                      an inert, diluent gas, such as helium or, more infrequently nitrogen, is
                      used to increase the flow mixture’s heat capacity, thus minimizing the
                      effects  of  heat  release. Alternatively,  one  can  mitigate  heat  release
                      through area expansion; however, this increases vacuum pumping
                      demands. Figures 3.10 to 3.12 show the Mach number, temperature,
                      and pressure dependence of the gas mixture as a function of position
                      in a typical laser cavity with and without the addition of heat due to
                      the secondary flow.
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