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HYDC06  12/5/05  5:33 PM  Page 198






                 198    Chapter Six


                 Table 6.1 Potential sources of groundwater pollution arising from domestic, industrial and agricultural activities. Adapted from
                 Jackson (1980).
                 Contaminant source             Contaminant characteristics
                 Septic tanks                   Suspended solids  100–300 mg L −1
                                                BOD         50–400 mg L −1
                                                Ammonia     20–40 mg L −1
                                                Chloride    100–200 mg L −1
                                                High faecal coliforms and streptococci
                                                Trace organisms, greases
                 Storm water drains             Suspended solids  ~ 1000 mg L −1
                                                Hydrocarbons from roads, service areas
                                                Chlorides or urea from de-icing
                                                Compounds from accidental spillages
                                                Bacterial contamination
                 Industry
                  Food and drink manufacturing  High BOD. High suspended solids. Colloidal and dissolved organic substances. Odours
                  Textile and clothing          High suspended solids and BOD. Alkaline effluent
                  Tanneries                     High BOD, total solids, hardness, chlorides, sulphides, chromium
                  Chemicals
                    Acids                       Low pH
                    Detergents                  High BOD
                    Pesticides                  High TOC, toxic benzene derivatives, low pH
                    Synthetic resins and fibres  High BOD
                  Petroleum and petrochemical
                    Refining                     High BOD, chloride, phenols, sulphur compounds
                    Process                     High BOD, suspended solids, chloride, variable pH
                  Plating and metal finishing    Low pH. High content of toxic metals
                  Engineering works             High suspended solids, hydrocarbons, trace heavy metals. Variable BOD, pH
                  Power generation              Pulverized fuel ash: sulphate, and may contain germanium and selenium. Fly ash and flue
                                                gas scrubber sludges: low pH, disseminated heavy metals
                  Deep well injection           Concentrated liquid wastes, often toxic brines. Acid and alkaline wastes. Organic wastes
                  Leakage from storage tanks and pipelines  Aqueous solutions, hydrocarbons, petrochemicals, sewage
                 Agriculture
                  Arable crops                  Nitrate, ammonia, sulphate, chloride and phosphates from fertilizers. Bacterial
                                                contamination from organic fertilizers. Organochlorine compounds from pesticides
                  Livestock                     Suspended solids, BOD, nitrogen. High faecal coliforms and streptococci
                                                                       4
                  Silage                        High suspended solids, BOD 1–6 × 10 mg L −1
                                                Carbohydrates, phenols
                 Mining
                  Coal mine drainage            High TDS (total dissolved solids), suspended solids. Iron. Low pH. Possibly high chloride
                  Metals                        High suspended solids. Possibly low pH. High sulphates. Dissolved and particulate metals
                 Household wastes               High sulphate, chloride, ammonia, BOD, TOC and suspended solids from fresh wastes.
                                                Bacterial contamination. On decomposition: initially TOC of mainly volatile fatty acids
                                                (acetic, butyric, propionic acids), subsequently changing to high molecular weight
                                                organics (humic substances, carbohydrates)
                                                             +
                 BOD, biological oxygen demand; TOC, total organic carbon; pH, −log (H ).
                                                          10

                 the scientific information with which decisions on  political, legal and socioeconomic issues, policy
                 water quality can be based, for example toxicity data,  makers are able to set water quality objectives for the
                 information relating to the available water treat-  attainment of good quality.
                 ment technology and environmental degradation  For groundwater, the setting of chemical quality
                 rates. With this information, and taking into account  objectives may not always be the best approach since
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